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Reaction of 2-diethylamino-3-diethylaminomethyl-1,3,2-benzoxazaphospholine with hydroxyl-containing compounds

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Abstract

The reaction of 2-diethylamino-3-diethylaminomethyl-1,3,2-benzoxazaphospholine with functionally substituted alcohols and phenols occurs with the cleavage of exocyclic P-N bond followed by N→P migration of the diethylaminomethyl group and formation of imidophosphonate dimers. A similar reaction with polyhydroxy compounds (diethylene glycol, glycerol) results in symmetrical and asymmetrical spirophosphoranes.

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References

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan' Scientific Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420083, Kazan', Russian Federation

    M. A. Pudovik, S. A. Terent'eva, I. A. Litvinov, O. N. Kataeva, V. A. Naumov & A. N. Pudovik

Authors
  1. M. A. Pudovik
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  2. S. A. Terent'eva
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  3. I. A. Litvinov
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  4. O. N. Kataeva
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  5. V. A. Naumov
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  6. A. N. Pudovik
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Additional information

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1781–1784, October, 1993.

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Pudovik, M.A., Terent'eva, S.A., Litvinov, I.A. et al. Reaction of 2-diethylamino-3-diethylaminomethyl-1,3,2-benzoxazaphospholine with hydroxyl-containing compounds. Russ Chem Bull 42, 1706–1709 (1993). https://doi.org/10.1007/BF00697046

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  • DOI: https://doi.org/10.1007/BF00697046

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