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Reaction of 2-amino-4-imino-2-perfluoropentene with ethylenediamine and diethylenetriamine

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Russian Chemical Bulletin Aims and scope

Abstract

The transamination of 2-amino-4-imino-2-perfluoropentene with ethylenediamine gives the corresponding 6-fluoro-5,7-bis(trifluoromethyl)-2,3-dihydro-1H-1,4-diazepine. The transamination of 2-amino-4-imino-2-perfluoropentene by diethylenetriamine is accompanied by intramolecular nucleophilic substitution of the α-fluorine atom to form 1,9-bis(trifluoromethyl)-3,4,6,7-tetrahydro-2H-pyrazino[1,2-a]pyrazine whose structure was established by an X-ray structural investigation. Several salts of this bicyclic compound and its complex with BF3 have been described.

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References

  1. M. A. Kurykin, L. S. German, and I. L. Knunyants,Izv. Akad. Nauk SSSR, Ser. Khim., 1980, 2827 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1980,29 (Engl. Transl.)].

    Google Scholar 

  2. K. I. Pashkevich and V. I. Filyakova,Izv. Akad. Nauk SSSR, Ser. Khim., 1986, 620 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1986,35, 566 (Engl. Transl.)].

  3. K. I. Pashkevich, A. Ya. Aizikovich, and I. Ya. Postovskii,Izv. Akad. Nauk SSSR, Ser. Khim., 1981, 455 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1981,30 (Engl. Transl.)].

    Google Scholar 

  4. V. I. Saloutin, Z. E. Skryabina, and Ya. V. Bargart,Izv. Akad. Nauk, Ser. Khim., 1992, 2170 [Bull. Russ. Acad. Sci., Div. Chem. Sci., 1992,41, 1700 (Engl. Transl.)].

    Google Scholar 

  5. G. M. Sheldrick,Acta Cryst., 1990,A 46, 467.

    Google Scholar 

  6. Z. E. Skryabina, Ya. V. Burgart, and V. I. Saloutin,Izv. Akad. Nauk SSSR, Ser. Khim., 1991, 890 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1991,40, 788 (Engl. Transl.)].

    Google Scholar 

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Authors and Affiliations

  1. Institute of Organic Chemistry, Ural Branch of the Russian Academy of Sciences, 20 ul. S. Kovalevskoi, 620219, Ekaterinburg, Russian Federation

    V. I. Saloutin, Z. E. Skryabina, Y. V. Burgart & O. N. Chupakhin

  2. Department of Crystallography, Mineralogy, and Deposits, Barcelona University, 08028, Barcelona, Spain

    M. Font-Altaba, X. Solans & M. Font-Bardia

Authors
  1. V. I. Saloutin
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  2. Z. E. Skryabina
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  3. Y. V. Burgart
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  4. O. N. Chupakhin
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  5. M. Font-Altaba
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  6. X. Solans
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  7. M. Font-Bardia
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1773–1776, October, 1993.

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Saloutin, V.I., Skryabina, Z.E., Burgart, Y.V. et al. Reaction of 2-amino-4-imino-2-perfluoropentene with ethylenediamine and diethylenetriamine. Russ Chem Bull 42, 1697–1700 (1993). https://doi.org/10.1007/BF00697043

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  • DOI: https://doi.org/10.1007/BF00697043

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