Skip to main content
SpringerLink
Log in

Oxidative interactions of propene with acetic acid on a Pd-zeolite catalyst

  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

The interactions between C3H6, AcOH and O2 were investigated on 1.5 % Pd/TsVM catalysts prepared with and without addition of 15 % AcOK. Three states for surface oxygen on the promoted catalyst were distinguished. Two of them are involved in the oxidation of AcOH and C3H6 to CO2 and H2O, whereas the adsorbed species of the third type participates in the formation of allyl acetate. The O/Pd ratios for the promoted catalyst fall in the range from 3 to 4, the nonpromoted system is characterized by an O/Pd value of 0.5. IR-spectral data are used to discuss the reaction scheme for the formation of allyl acetate.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Kh. M. Minachev and V. V. Kharlamov,Proc. Intern. Symp. on Zeolite Catalysis, Siofok, Hungary, 1985, 497.

    Google Scholar 

  2. Kh. M. Minachev, V. V. Kharlamov, and T. S. Starostina,Kinet. Katal., 1990,31, 630 [Kinet. Catal., 1990,31, 550 (Engl. Transl.)].

    CAS  Google Scholar 

  3. Kh. M. Minachev, O. M. Nefedov, V. V. Kharlamov, O. S. Chizhov, A. P. Rodin, and V. I. Kadentsev,Izv. Akad. Nauk SSSR, Ser. Khim., 1985, 1253 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1985,34, 1146 (Engl. Transl.)].

  4. A. W. Davidson and W. H. McAllister,J. Am. Chem. Soc., 1930,52, 509.

    Google Scholar 

  5. J. B. Utterhoeven, R. Schoonheydt, B. V. Liengme, and W. K. Hall,J. Catal., 1969,13, 425.

    Article  Google Scholar 

  6. J. Haber, J. Komorek-Hlodzik, and T. Romotowski,Zeolites, 1982,2, 179.

    Article  CAS  Google Scholar 

  7. L. H. Little,Infrared Spectra of Adsorbed Species, Academic Press, London, 1967.

    Google Scholar 

  8. J. Ward, inZeolite Chemistry and Catalysis, Ed. J. A. Rabo, ACS Monograph 171, Washington, D.C. 1976, 200.

  9. M. Ayyobb and M. S. Hegde,Surf. Sci., 1983,133, 516.

    Article  Google Scholar 

  10. M. Ayyobb and M. S. Hegde,Surf. Sci., 1984,147, 361.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation

    Kh. M. Minachev, T. S. Starostina & V. V. Kharlamov

  2. Institute of Catalysis and Surface Chemistry, Polish Academy of Sciences, ul. Niezapominajek, 30239, Krakow, Poland

    J. Komorek & T. Romotowski

Authors
  1. Kh. M. Minachev
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. T. S. Starostina
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. V. Kharlamov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. J. Komorek
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. T. Romotowski
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1721–1726, October, 1993.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Minachev, K.M., Starostina, T.S., Kharlamov, V.V. et al. Oxidative interactions of propene with acetic acid on a Pd-zeolite catalyst. Russ Chem Bull 42, 1643–1648 (1993). https://doi.org/10.1007/BF00697031

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00697031

Key words

Search

Navigation