Abstract
Thallous dicarbollide reacts with cobalt(II), iron(III) and chromium(III) chlorides without a solvent under conditions of mechanical activation to form the corresponding carborane complexes of tervalent metals.
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References
M. F. Hawthorne,Acc. Chem. Res., 1968,1, 281.
A. P. Borisov and V. D. Makhaev, inMekhanokhimicheskiy sintez v neorganicheskoy khimii (Mechanochemical Synthesis in Inorganic Chemistry), Ed. E. G. Awakumov, Nauka, Novosibirsk, 1991, 165 (in Russian).
Yu. V. Karyakin and I. I. Angelov,Chistye khimicheskie vechchestva (Pure Chemical Substances), Khimiya, Moscow, 1974 (in Russian).
J. L. Spencer, M. Green, and F. G. A. Stone,J. Chem. Soc., Chem.Commun., 1972, 1178.
N. N. Greenwood, L. D. Kennedy, and X. L. R. Fontaine,J. Chem. Soc., Dalton Trans., 1990, 681.
M. F. Hawthorne, D. G. Young, T. D. Andrews, D. V. Howe, R. L. Pilling, D. S. Pitts, M. Reintjes, L. F. Warren, and P. A. Wegner,J. Am. Chem. Soc., 1968,90, 879.
V. V. Volkov and K. G. Myakishev, inKhimiya neorganicheskikh gidridov (The Chemistry of Inorganic Hydrides), Ed. N. T. Kuznetsov, Nauka, Moscow, 1990 (in Russian).
U. Mirsaidov, M. S. Pulatov, Kh. Aliev, and M. Khikmatov, inMekhanokhimicheskii sintez v neorganicheskoi khimii (Mechanochemical Syntheses in Inorganic Chemistry), Ed. E. G. Awakumov, Nauka, Novosibirsk, 1991 (in Russian).
L. I. Mirkin,Spravochnik po rentgenostruktumomu analizu polikristallov (Guide to X-ray Structural Analysis of Polycrystals), Gos. Izd-vo Phyz.-Mat. Lit., Moscow, 1961 (in Russian).
H. W. Ruhle and M. F. Hawthorne,Inorg. Chem., 1968,7, 2279.
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1715–1717, October, 1993.
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Borisov, A.P., Makhaev, V.D., Usyatinskii, A.Y. et al. Solid-state mechanochemical synthesis of cobalt(III), iron(III), and chromium(III) bisdicarbollyl complexes. Russ Chem Bull 42, 1637–1639 (1993). https://doi.org/10.1007/BF00697029
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DOI: https://doi.org/10.1007/BF00697029