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Russian Chemical Bulletin

, Volume 44, Issue 1, pp 140–144 | Cite as

Synthesis of carborane-containing phosphates by catalytic phosphorylation

  • M. I. Kabachnik
  • L. S. Zakharov
  • E. L. Gefter
  • G. N. Molchanova
  • Yu. T. Struchkov
  • A. I. Yanovsky
  • A. V. Polyakov
  • P. V. Petrovskii
Organic Chemistry

Abstract

The catalytic phosphorylation ofo-carboranylmethanol with different phosphorus acid chlorides has been studied. This method makes it possible to obtain esters of phosphorus acids and esters of the corresponding phosphorus acid chlorides containing carboranylmethyl groups. The catalytic phosphorylation of 1,2-bis(hydroxymethyl)-o-carborane affords both acyclic and cyclic phosphate esters. The structure of the synthesizedo-carborano[1,2-e]-1,3,2-dioxaphosphepane was confirmed by X-ray diffraction analysis.

Key words

o-carboranylmethanol, 1,2-bis(hydroxymethyl)-o-carborane catalytic phosphorylation phosphate esters 

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References

  1. 1.
    E. G. Rys, N. N. Godovikov, and M. I. Kabachnik,Izv. Akad. Nauk SSSR, Ser. Khim., 1983, 2640 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1983,32, 2372 (Engl. Transl.)].Google Scholar
  2. 2.
    USSR Pat. 394379,Byul. Izobret., 1973, No. 34 (in Russian).Google Scholar
  3. 3.
    L. I. Zakharkin, A. I. Kovredov, A. V. Kazantsev, and M. G. Meiramov,Zh. Obshch. Khim., 1981,51, 357 [J. Gen. Chem. USSR, 1981,51 (Engl. Transl.)].Google Scholar
  4. 4.
    A. V. Kazantsev, M. G. Meiramov, A. I. Kovredov, and L. I. Zakharkin,Izv. Akad. Nauk SSSR, Ser. Khim., 1982, 1603 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1982,31, 1425 (Engl. Transl.)].Google Scholar
  5. 5.
    L. S. Zakharov, V. V. Pisarenko, N. N. Godovikov, and M. I. Kabachnik,Izv. Akad. Nauk SSSR, Ser. Khim., 1971, 2503 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1971,20, 2373 (Engl. Transl.)].Google Scholar
  6. 6.
    M. I. Kabachnik, L. S. Zakharov, E. L. Gefter, G. N. Molchanova, and P. V. Petrovskii,Izv. Akad. Nauk SSSR, Ser. Khim., 1990, 1933 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1990,39, 1759 (Engl. Transl.)].Google Scholar
  7. 7.
    E. E. Nifant'ev, T. Yu. Prokofeva, R. K. Magdeeva, L. S. Sklyarskii, and K. D. Galstyan, Zh.Obshch. Khim., 1982, 52, 217 [J. Gen. Chem. USSR, 1982,52 (Engl. Transl.)].Google Scholar
  8. 8.
    V. V. Korshak, N. I. Bekasova, and M. P. Prigozhina,Izv. Akad. Nauk SSSR, Ser. Khim., 1986, 2128 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1986,35, 1940 (Engl. Transl.)].Google Scholar
  9. 9.
    C. L. Coulter,J. Am. Chem. Soc., 1975,97, 4084.Google Scholar
  10. 10.
    V. S. Mastryukov, O. V. Dorofeeva, and L. V. Vilkov,Usp. Khim., 1980,49, 2377 [Russ. Chem. Rev., 1980,49 (Engl. Transl.)].sGoogle Scholar

Copyright information

© Plenum Publishing Corporation 1995

Authors and Affiliations

  • M. I. Kabachnik
    • 1
  • L. S. Zakharov
    • 1
  • E. L. Gefter
    • 1
  • G. N. Molchanova
    • 1
  • Yu. T. Struchkov
    • 1
  • A. I. Yanovsky
    • 1
  • A. V. Polyakov
    • 1
  • P. V. Petrovskii
    • 1
  1. 1.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussian Federation

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