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Russian Chemical Bulletin

, Volume 44, Issue 1, pp 113–115 | Cite as

Synthesis and transformations of metallocycles

15. A novel method for β-vinylation of α-olefins with AlEt3 under the action of Ni- and Zr-containing catalysts
  • A. G. Ibragimov
  • A. P. Zolotarev
  • R. R. Muslukhov
  • S. I. Lomakina
  • U. M. Dzhemilev
Organic Chemistry

Abstract

A novel regioselective method has been developed for the synthesis of 2-substituted 1,3-butadienes by β-vinylation of α-olefins with AlEt3 in the presence of Ni- and Zr-containing catalysts.

Key words

dienes, synthesis nickel complexes, catalysts allyl compounds organoaluminum compounds 

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Copyright information

© Plenum Publishing Corporation 1995

Authors and Affiliations

  • A. G. Ibragimov
    • 1
  • A. P. Zolotarev
    • 1
  • R. R. Muslukhov
    • 1
  • S. I. Lomakina
    • 1
  • U. M. Dzhemilev
    • 1
  1. 1.Institute of Petrochemistry and CatalysisAcademy of Sciences of Republic BashkortostanUfaRussian Federation

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