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[2+2+2] Cycloaddition reaction with the participation of unsaturated ketones catalyzed by an Rh(i)—Sn(ii) system

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Abstract

Codimerization of vinyl ketones with metallylacetone or metallylacetophenone in the presence of [RhCl(C2H4)2]2-SnCl2 affords substitutedendo-2-acyl-8-oxabicyclo[3.2.1]octanes, the products of the formal [2+2+2] cycloaddition.

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation

    Yu. A. Strelenko, V. V. Ipatkin, I. P. Kovalev & G. I. Nikishin

Authors
  1. Yu. A. Strelenko
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  2. V. V. Ipatkin
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  3. I. P. Kovalev
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  4. G. I. Nikishin
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Additional information

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2280–2283, November, 1995.

We thank Uve Ihhoff (Moscow Representative of Bruker GmbH) for the provision of their AMX 400 spectrometer.

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Strelenko, Y.A., Ipatkin, V.V., Kovalev, I.P. et al. [2+2+2] Cycloaddition reaction with the participation of unsaturated ketones catalyzed by an Rh(i)—Sn(ii) system. Russ Chem Bull 44, 2187–2189 (1995). https://doi.org/10.1007/BF00696730

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  • DOI: https://doi.org/10.1007/BF00696730

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