Abstract
Reactions of haloarenes with urotropine in CF3COOH at elevated temperatures and high pressures give the corresponding aromatic aldehydes and/orN-(haloarylmethyl)trifluoroacetamides. The yeilds of the products and their ratio depend on electronic properties of substituents in the aromatic ring. The reaction carried out in a mixture of CF3COOH and (CF3CO)2O affords only amides.
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2221–2224, November, 1995.
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Sedishev, I.P., Agafonov, N.E., Kutin, A.A. et al. Haloarenes in the Duff reaction under high pressures. Russ Chem Bull 44, 2127–2130 (1995). https://doi.org/10.1007/BF00696718
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DOI: https://doi.org/10.1007/BF00696718