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Evaluation of jet-cooled laser spectroscopy for simplifying infrared spectra

Results for CO, PF3, CF3Cl, cyclopropane, vinyl fluoride, and methylacetylene (propyne)

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Abstract

The effect of jet cooling on the vibration-rotation spectra of several polyatomic molecules has been investigated using diode-laser absorption spectroscopy. Vibration-rotation spectra in jet expansions is considered in terms of several factors including rotational and vibrational distributions, line strengths and the rotational structure of individual bands. The diode-laser spectra of PF3, CF3Cl, C3H6, C2H3F, and CH3CCH recorded in a molecular beam are examined with the above criteria.

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Author notes

  1. A. J. Morton-Jones

    Present address: Corporate Colloid Science Group, ICI plc, The Heath, P.O. Box 11, Runcorn, Cheshire, UK

Authors and Affiliations

  1. Department of Physical Chemistry, University of Cambridge, Lensfield Road, CB2 1EP, Cambridge, UK

    P. B. Davies & A. J. Morton-Jones

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  1. P. B. Davies
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  2. A. J. Morton-Jones
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Davies, P.B., Morton-Jones, A.J. Evaluation of jet-cooled laser spectroscopy for simplifying infrared spectra. Appl. Phys. B 42, 35–40 (1987). https://doi.org/10.1007/BF00694771

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  • DOI: https://doi.org/10.1007/BF00694771

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