Conclusions
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1.
Ferromagnetic carbides of the cementite type are present in the steel after quenching (without tempering) and after tempering at temperatures below 620° for 1 h. Carbides of the cementite type have the shape of thin platelets with a length up to 100 Å (tempering at 200°), up to 1000 Å (tempering at 350°), and up to 2000 Å (tempering at 500° and higher).
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2.
MC secondary carbides (VC) are precipitated in the process of tempering at temperatures ≥540°. The electrochemical properties of these dispersed carbides and MC carbides differ greatly after quenching or annealing. The properties become similar with increasing tempering temperatures.
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3.
M2C secondary carbides and chromium carbides are precipitated during tempering at 560–580° and higher, and M6C carbides with tempering above 640–650°. No preferential precipitation of special carbides on cementite particles or the boundaries of martensite crystals, twins, or other lattice defects was observed.
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4.
Precipitation of special carbides is accompanied by a reduction of the austenite and martensite lattice constant. Formation of M6C carbides is observed after almost complete isothermal transformation of retained austenite and reduction of the lattice constant of α phase to a value close to that obtained after annealing.
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Additional information
All-Union Scientific-Research Tool Institute. Translated from Metallovedenie i Termicheskaya Obrabotka Metallov, No. 7, pp. 55–60, July, 1980.
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Kupalova, I.K. Transformations in high-speed steels during tempering. Met Sci Heat Treat 22, 522–527 (1980). https://doi.org/10.1007/BF00693598
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DOI: https://doi.org/10.1007/BF00693598