Skip to main content
SpringerLink
Log in

Synthesis and electrochemical properties of a polynorbornene derivative containing a carbazole moiety

  • Published:
Polymer Bulletin Aims and scope Submit manuscript

Summary

A new polymer, poly {5-[[(6-N-carbazoylhexyl)oxy]methyl]-2-norbornene} [Poly (NCHN)], was synthesized by ring-opening metathesis polymerization (ROMP) with various transition metal catalyst systems. The structure of the poly (NCHN) was analyzed by NMR, IR, and UV-vis spectroscopy. The electrochemical properties of the poly (NCHN) were characterized by cyclic voltammetric technique. From the cyclic voltammetric results it was concluded that the carbazole units in side chain of the polymer were oxidized and coupled irreversibly to form dicarbazyls. The redox kinetics was mainly controlled by both electron transfer and ClO4 - diffusion processes preserving the electro-neutrality of the polymer.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. R.M.Schaffert, IBM, J.Rev.Develop15, 75 (1975)

    Google Scholar 

  2. H.Naarmann, D.Strohriegel, in “Handbook of Polymer synthesis,” ed. by H.R.Kricheldorf, Marcel Dekker, Inc, New York, 1404 (1992)

    Google Scholar 

  3. M.Stolka and D.M.Pai, “Advances in Polymer Science,” ed. by H.-J.Cantow et al. Springer-Verlag Berlin Heidelberg, New York,29 1 (1978)

    Google Scholar 

  4. J.W.Park, J.H.Lee, H.N.Cho, and S.K.Choi, Macromolecules26 1191 (1993)

    Google Scholar 

  5. G.Helary, C.Chevrot, G.Sauvet, and A.Siove, Polym.Bulletin26 131 (1993)

    Google Scholar 

  6. B.R.Hsieh, M.H.Litt, Macromolecules19 521 (1986)

    Google Scholar 

  7. J.F.Ambrose and R.F.Nelson, J.Electrochem.Soc115 1159 (1968)

    Google Scholar 

  8. J.F.Ambrose, L.L.Carpenter, and R.F.Nelson, J.Electrochem.Soc122 876 (1975)

    Google Scholar 

  9. H.F.Ardill, J.J.Rooney, in “Ring-Opening Polymerization” ed by J.E.McGrath, ACS Symposium series286 275 (1985)

  10. S.H.Kim, H.J.Lee, S.H.Jin, H.N.Cho, and S.K.Choi, Macromolcules26 846 (1993)

    Google Scholar 

  11. J.M.Ko, H.W.Rhee, and S.M.Park, J.Electrochem.Soc 137 (3) 905 (1990)

    Google Scholar 

  12. H.N.Cho, K.Y.Choi, and S.K.Choi, J.Polym.Sci., Polym.Chem.23 1469 (1985)

    Google Scholar 

  13. G.C.Bazan, R.R.Schrock, H.N.Cho, and V.C.Gibson, Macromolecules24 4495 (1991)

    Google Scholar 

  14. A.J.Bard, L.R.Faulker, “Electrochemical Methods” Chapter 3,6, and 10, Wiley, New York (1980)

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Korea Advanced Institute of Science and Technology, 373-1 Kusung-Dong, 305-701, Yusong-Gu, Taejon, Korea

    Ji-Hoon Lee, Jong-Wook Park, Young-Hwan Chang & Sam-Kwon Choi

  2. R&D Center, HanKook Tire Mfg.Co., 305-701, Yusong-Gu, Taejon, Korea

    J. M. Ko

Authors
  1. Ji-Hoon Lee
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Jong-Wook Park
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. J. M. Ko
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Young-Hwan Chang
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Sam-Kwon Choi
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Lee, JH., Park, JW., Ko, J.M. et al. Synthesis and electrochemical properties of a polynorbornene derivative containing a carbazole moiety. Polymer Bulletin 31, 339–346 (1993). https://doi.org/10.1007/BF00692961

Download citation

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00692961

Keywords

Search

Navigation