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High-resolution spectroscopy of CF2Cl2 in a molecular jet

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Abstract

Absorption spectra of CF2Cl2 were recorded around 923 cm−1, with a resolution of 50 MHz. The application of the molecular jet technique considerably simplifies the spectra as compared to room-temperature experiments. Rotational and vibrational temperatures were measured for CF2Cl2 pure and seeded in Ar or He. Molecular constants were obtained for thev 6 vibrational band of the two most abundant chlorine isotopic species, as well as vibrational band origines for thev 6±v 4 and thev 6±v 5 hot-bands of the CF2 35Cl2 isotope.

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Authors and Affiliations

  1. ENEA, Dipartimento TIB, U.S. Fisica Applicata, CRE Frascati, CP65, I-00044, Frascati (Roma), Italy

    M. Snels

  2. Fysisch Laboratorium, Katholieke Universiteit, Toernooiveld, NL-6525 ED, Nijmegen, The Netherlands

    W. L. Meerts

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  1. M. Snels
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  2. W. L. Meerts
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Snels, M., Meerts, W.L. High-resolution spectroscopy of CF2Cl2 in a molecular jet. Appl. Phys. B 45, 27–31 (1988). https://doi.org/10.1007/BF00692337

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