Journal of Applied Electrochemistry

, Volume 1, Issue 4, pp 269–274 | Cite as

An evaluation of integration procedures for improving the precision of a.c. polarography

  • B. Fleet
  • R. D. Jee


Two integration procedures for improving the precision of a.c. polarography have been studied. Both methods are single electrode techniques and involve integration of the rectified a.c. current over the complete peak or at the peak potential respectively. The time integration procedure was found to be seriously influenced by small variations in the reference electrode potential and applied voltage, resulting in poor reproducibility between different samples. In the area integration procedure, however, where the accurate control of potential is less critical, the standard deviation between replicate samples was found to be within the statistically expected limits and this method was therefore preferred. Standard deviations were measured for a range of inorganic and organic species and typical values of ±0.25% at the optimum concentration level (4.10−4M) were obtained.


Reference Electrode Concentration Level Applied Voltage Small Variation Time Integration 
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Copyright information

© Chapman and Hall Ltd. 1971

Authors and Affiliations

  • B. Fleet
    • 1
  • R. D. Jee
    • 1
  1. 1.Chemistry DepartmentImperial College of Science and TechnologyLondon

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