Skip to main content
SpringerLink
Log in

Synthesis and thermal properties of zirconium ortho- and diphosphates

  • Papers
  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

Single phase sodium zirconium orthophosphates [NaZr2(PO4)3 and Na2Zr(PO4)2] and zirconium diphosphate (ZrP2O7) have been synthesized. The measured linear expansion coefficient of NaZr2(PO4)3 was rather small only reaching a value of 0.16% at 800 °C. The expansion coefficients of Na2Zr(PO4)2 and ZrP2O7 were also rather small and were 1.4 and 1.0% respectively at 800 °C. These phosphates showed different behaviour depending on the type of thermal pretreatment before the measurement of the expansion coefficient.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. J. R. VAN WAZER, “Phosphorus and its compounds”, Vols. I and II (Interscience Publishers, New York 1961).

    Google Scholar 

  2. D. E. C. CORBRIDGE, “Phosphorus” (Elsevier, Amsterdam, Oxford, New York, 1980).

    Google Scholar 

  3. A. D. F. TOY and E. N. WALSH, “Phosphorus chemistry in everyday living” (Amer. Chem. Soc., Washington, DC, 1987).

    Google Scholar 

  4. T. KANAZAWA, “Inorganic phosphate materials” (Elsevier, Amsterdam, Oxford, New York, Tokyo, 1989).

    Google Scholar 

  5. J. ALAMO and R. ROY,J. Mater. Sci. 21 (1986) 444.

    Article  CAS  Google Scholar 

  6. G. E. LENAIN, H. A. MCKIMSTRY, J. ALAMO, and D. K. AGRAWAL,ibid. 22 (1987) 17.

    Article  CAS  Google Scholar 

  7. T. OTA and I. YAMAI,J. Amer. Ceram. Soc. 69 (1986) 1.

    Article  Google Scholar 

  8. N. KATAGIRI, Y. HATTORI, T. OTA, and I. YAMAI,J. Ceram. Soc. Jpn. 102 (1994) 69.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Industrial Chemistry, College of Engineering, Chubu University, Matsumotocho, Kasugai, 487, Aichi, Japan

    Makoto Watanabe, Makoto Sakurai, Tetsuya Yamada & Hidehiko Mori

Authors
  1. Makoto Watanabe
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Makoto Sakurai
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Tetsuya Yamada
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Hidehiko Mori
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Watanabe, M., Sakurai, M., Yamada, T. et al. Synthesis and thermal properties of zirconium ortho- and diphosphates. J Mater Sci 31, 2569–2572 (1996). https://doi.org/10.1007/BF00687283

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00687283

Keywords

Search

Navigation