Abstract
Recent advances in the various theories of strain-birefringenece of polymer networks are presented. The classical theories as well as the more advanced models are outlined together with some recent theoretical results on poly (dimethylsiloxane). Reference to work on other Si-containing polymers is made. The problems of intermolecular correlations occurring in polymer networks and their effect on the observed optical properties are discussed with reference to the optical-configuration parameter. Conclusions report areas of current research.
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References
J. E. Mark and B. Erman,Rubberlike Elasticity. A Molecular Primer (Wiley-Interscience, New York, 1988).
V. Galiatsatos and J. E. Mark,Polym. Bull. 17, 197 (1987).
M. A. Llorente, I. F. de Pierola, and E. Saiz,Macromolecules 18, 2663 (1985).
M. A. Llorente, J. E. Mark, and E. Saiz,J. Polym. Sci. Polym. Phys. Ed. 21, 1173 (1983).
V. Galiatsatos and J. E. Mark,Macromolecules 20, 2631 (1987).
M. H. Lieberman, Y. Abe, and P. J. Flory,Macromolecules 5, 550 (1972).
L. R. G. Treloar,The Physics of Rubber Elasticity (Clarendon Press, Oxford, 1975).
H. M. James,J. Chem. Phys. 15, 651 (1947); H. M. James, and E. Guth,J. Chem. Phys. 15, 669 (1947).
B. Erman and P. J. Flory,Macromolecules 15, 800 (1982).
G. Ronca and G. Allegra,J. Chem. Phys. 63, 4990 (1975).
P. J. Flory,Proc. R. Soc. London Ser. A 351, 351 (1976).
B. Erman and P. J. Flory,Macromolecules 16, 1601 (1983).
P. J. Flory,Statistical Mechanics of Chain Molecules (Interscience, New York, 1969).
J. P. Queslel, P. Thirion, and L. Monnerie,Polymer 27, 1869 (1986).
B. Erman and J. E. Mark,Macromolecules 20, 2892 (1987).
V. Galiatsatos,Macromolecules 23, 3821 (1990).
D. S. Pearson,Macromolecules 10, 696 (1977).
B. Erman, A. Kloczkowski, and J. E. Mark,Macromolecules 22, 1432 (1989).
F. Fontaine, C. Morland, C. Noel, L. Monnerie, and B. Erman,Macromolecules 22, 3348 (1989).
F. Fontaine, C. Noel, L. Monnerie, and B. Erman,Macromolecules 22, 3352 (1989).
P. J. Flory,Macromolecules 7, 381 (1974).
B. Erman and P. J. Flory,Macromolecules 16, 1607 (1983).
G. Floudas, G. Fytas, B. Momper, and E. Saiz,Macromolecules 23, 498 (1990).
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Galiatsatos, V. Recent advances in the rheooptical characterization of silicon-containing networks. J Inorg Organomet Polym 1, 449–462 (1991). https://doi.org/10.1007/BF00683511
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DOI: https://doi.org/10.1007/BF00683511