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Structural Chemistry

, Volume 2, Issue 3–4, pp (69)277–(72)280 | Cite as

Mössbauer spectroscopy of liquid SnCl4 solutions trapped in a rigid microemulsion

  • K. Burger
  • A. Vértes
  • I. Dékány
  • Zs. Nemes-Vetéssy
Article

Abstract

A rigid microemulsion was prepared containing submicroscopic droplets of liquid aqueous tin tetrachloride solution. Recoillessγ-ray resonance absorption (the Mössbauer effect] was achieved in this system, indicating that the organic dispersion medium of the microemulsion behaved as a carrier, enhancing the Debye-Waller factor for the quasiliquid phase of the system. The Mössbauer spectra reflected the presence of two types of tin(IV) in the cavities of the microemulsion: SnCl4 species situated in the bulk solution and on the cavity wall, respectively.

Keywords

Spectroscopy Physical Chemistry Dispersion Medium Tetrachloride Bulk Solution 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

References

  1. 1.
    Burger, K.; Vértes, A.Nature (London) 1983,306, 353.Google Scholar
  2. 2.
    Burger, K.; Vértes, A.; Suba, M.; Dékány, I.Inorg. Chim. Acta 1985,100, 17.Google Scholar
  3. 3.
    Burger, K.Spectrochim. Acta A 1987,43, 1105.Google Scholar
  4. 4.
    Burger, K.; Nemes-Vetéssy, Zs.; Vértes, A.; Suba, M.; Knausz, D.Inorg. Chim. Acta 1988,148, 223.Google Scholar
  5. 5.
    Frieberg, S. E. InMicroemulsions: Theory and Practice; Prince, L. M., Ed.; Academic Press: London, 1977, Chap. 6, p. 133.Google Scholar
  6. 6.
    Langevin, D. InMicroemulsions: Structure and Dynamics; Frieberg, S. E.; Bothorel, P., Eds.; CRC Press: Florida, 1987, Chap. 7, p. 173.Google Scholar
  7. 7.
    Vértes, A.Acta Chim. Acad. Sci. Hung. 1970,63, 9.Google Scholar

Copyright information

© VCH Publishers, Inc 1991

Authors and Affiliations

  • K. Burger
    • 1
  • A. Vértes
    • 2
  • I. Dékány
    • 3
  • Zs. Nemes-Vetéssy
    • 4
  1. 1.Department of Inorganic and Analytical ChemistryA. József UniversitySzegedHungary
  2. 2.Laboratory of Nuclear ChemistryL. Eötvös UniversityBudapestHungary
  3. 3.Department of Colloid ChemistryA József UniversitySzegedHungary
  4. 4.Department of Inorganic and Analytical ChemistryA. József UniversitySzegedHungary

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