Conclusions
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1.
The lamellar crystals of carbide (Fe, Mo)6C formed during slow solidification (as low as 2 deg/min) of Fe-Mo-C alloys (30–40% Mo and 1.5–1.7% C) are rotation twins (twins along [111]).
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2.
In the transition zone — the area of mating of the components of the η twin — the regular alternation of the double layers of the structural elements (octahedron — octahedron, tetrahedron — tetrahedron) is disrupted, which leads to stacking faults.
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3.
After special etching, the area of the stacking fault is clearly revealed in metallographic analysis as planar boundaries dividing the crystals.
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4.
The fitting of the twin components in the process of growth is accompanied by substantial elastic stresses that induce cracks in twinned η crystals.
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Additional information
Institute of Ferrous Metallurgy. Translated from Metallovedenie i Termicheskaya Obrabotka Metallov, No. 11, pp. 49–53, November, 1977.
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Taran, Y.N., Nesterenko, A.M. Structure of M6C carbide in cast high-speed steels of the Fe-Mo-C system. Met Sci Heat Treat 19, 970–973 (1977). https://doi.org/10.1007/BF00670169
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DOI: https://doi.org/10.1007/BF00670169