Abstract
The oxidation of type 304L stainless steel at 600 K in air was studied using a number of surface-analytical techniques, including Auger electron spectroscopy (AES), scanning electron microscopy with energy-dispersive analysis of X-rays (SEM-EDAX), secondary ion mass spectrometry (SIMS), and X-ray photoelectron spectroscopy (XPS). Spectral analysis showed that a duplex oxide was formed, the outer layer of which formed rapidly and was essentially iron (III) oxide. Beneath this was a mixed iron-chromium oxide. SIMS sputter-profile curves showed region of relatively low iron concentration in the oxide film at the metal-oxide interface. This resulted from the rapid diffusion of iron within the oxide film. The oxide grain boundaries were examined using SEMEDAX. Higher chromium and silicon levels were detected in these regions compared with the corresponding grain centers. AES indicated the presence of silicon as SiO2.
Similar content being viewed by others
References
R. K. Wild,Corros. Sci. 17, 87 (1977).
R. Schubert,J. Vac. Sci. Technol. 12, 505 (1975).
S. Storp and R. Holm,Surface Sci. 68, 10 (1977).
B. Brox and I. Olefjord,Stainless Steels 84 (Institute of Metals, Gothenburg, 1985), p. 134.
G. C. Allen, P. A. Tempest, J. W. Tyler, and R. K. Wild,Oxid. Met. 21, 187 (1984).
I. Olefjord,Met. Sci. 9, 263 (1975).
D. R. Baer,Applic. Surface Sci. 7, 69 (1981).
G. Betz, G. K. Wehner, L. Toth, and A. Joshi,J. Appl. Phys. 45, 5312 (1974).
G. C. Allen, B. R. Bowsher, S. Dickinson, G. M. Fotios, A. L. Nichols, and R. K. Wild,Oxid. Met. 28, 33 (1987).
G. L. Briant and R. A. Mulford,Metall Trans. 13A, 745 (1982).
A. G. Matheuson,Vacuum 24, 505 (1977).
T. Tanabe and S. Imoto,Trans. Jn. Inst. Met. 20, 507 (1979).
R. K. Wild,Vacuum 26, 441 (1976).
G. C. Allen, P. M. Tucker, and R. K. Wild,J. Chem. Soc. Faraday Trans. II,74, 1126 (1978).
G. C. Allen, P. M. Tucker, and R. K. Wild,Philos. Mag. B 48, 411 (1982).
G. C. Allen, P. M. Tucker, and R. K. Wild,Oxid. Met. 13, 223 (1979).
C. D. Wagner, L. E. Davis, M. V. Zeller, J. A. Taylor, R. M. Raymond, and L. H. Galeg,Surface Interface Anal. 3, 211 (1981).
G. C. Allen, J. M. Dyke, S. J. Harris, and A. Morris,Appl. Surf. Sci.,31, 220 (1988).
The Oxide Handbook (IFI/Plenum, Samsonov, 1973).
L. V. Azaroff,J. Appl. Phys. 32, 1638 (1961).
J. B. Dunitz and L. E. Orgel,J. Phys. Chem. Solids 3, 20; 318 (1957).
T. J. Driscoll and P. B. Needham, Jr.,Oxid. Met. 13, 203 (1979).
M. E. Pick, A. G. Warner, and M. S. Kelland, TPRD/B/0856/R86.
A. M. Stoneham and M. J. L. Sangster,Philos. Mag. B 52, 717 (1985).
Dimenta-82, Diffusion in Metals and Alloys, Diffusion and Defect Monograph No. 7, Sept. 1982, article by N. L. Peterson, p. 145.
G. C. Allen and R. K. Wild,Philos. Mag. A 48, 373 (1983).
H. H. Madden,J. Vac. Sci. Technol. 18, 677 (1981).
N. Birks and G. H. Maer,Introduction to High Temperature Oxidation of Metals (Arnold, London, 1983).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Allen, G.C., Dyke, J.M., Harris, S.J. et al. A surface study of the oxidation of type 304L stainless steel at 600 K in air. Oxid Met 29, 391–408 (1988). https://doi.org/10.1007/BF00666841
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF00666841