Abstract
Dynamic light scattering and viscometry measurements have been carried out on three AB diblock copolymers in water/propan-2-ol mixtures. The A moieties in each case were poly(2-vinylpyridine-1-oxide) for which both water and propan-2-ol are good solvents. The B Moieties were either polystyrene or polydimethylsiloxane, for which both water and propan-2-ol are poor solvents, but water is the worse solvent. In all cases, the hydrodynamic size of the micelles (assumed spherical) was found to increase with increasing water content in the solvent mixture; the aggregation number was also found to increase. The former finding is in agreement with the theoretical predictions of Munch and Gast, but not the latter.
Similar content being viewed by others
References
Price C (1982) In: Developments in Block Copolymers Vol. 1, Goodman I (Ed.), Appl Sci Pub
Shibayama M, Hishimoto T, Kwai H (1983) Macromolecules 16:16, 361, 1093, 1427, 1434
Periard J, Riess G (1973) Eur Polymer J 9:687
Riess G, Rogez D (1982) Amer Chem Soc Polymer Preprints 23:19
Selb J, Gallot Y, (1982) Makromol Chem 182:1491
Price C, Woods D (1986) Euro Polymer J 9:721
Rigby D, Roe RJ (1986) Macromolecules 19:721
Gallot Y, Selb J, Marie P, Rameau A (1982) Amer Chem Soc Polymer Preprints 23:16
Sadron C (1963) Ang Chem Int Ed 2:248
Barker MC, Vincent B (1984) Colloids and Surfaces 8:297
Liebler L, Orland H, Wheeler JC (1983) J Chem Phys 79:3550
Noolandi J, Hong KM (1983) Macromolecules 16:1443
Munch MR, Gast AP (1988) Macromolecules 21:1360
Van Lent B, Scheutjens JMHM (1989) Macromolecules 22:1931
This journal, preceeding paper (Part 1)
The journal, following paper (Part 3)
Scheutjens JMHM, Fleer GJ (1979) J Phys Chem 83:1619
Leermakers FAM, van der Schoot PPAM, Scheutjens JMHM, Lyklema J In: Surfactants in Solution, Modern Applications, Mittal KL (Ed.), (in press)
Hall DG, Pethica BA (1976) In: Non-ionic surfactants, Schieck MJ (Ed.), (Marcel Dekker NY) Ch 16
Peterson JM, Fixman M (1963) J Chem Phys 39:2516
Mon CY, Adleman SA (1978) J Chem Phys 69:3135
Bedeaux D, Kapral R, Mazur P (1979) Physica 88A:88
Batchelor GK (1977) J Fluid Mech 97:83
Simha R (1952) J Appl Phys 23:1020
Roovers J, Toporowski PM (1980) J Poly Sci (Physics) 18:1907
Tuzar Z, Plestil J, Kodak C, Hlavata D, Sikova R (1983) Macromol Chem 184:2111
Price C, McAdam JDG, Lally TP, Woods D (1974) Polymer 15:228
Marie P, Gallot Y (1977) CR Acad Sci (Paris) Ser C 284:327
Gallot Y, Selb J, Marie P, Rameau A (1982) Amer Chem Polymer Prep 23:16
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Biggs, S., Vincent, B. Poly(styrene-b-2-vinylpyridine-1-oxide) and poly(dimethyl-siloxane-b-2-vinylpyridine-1-oxide) diblock copolymers 2. Micellar solutions in water/propan-2-ol mixtures. Colloid Polym Sci 270, 511–517 (1992). https://doi.org/10.1007/BF00665997
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00665997