Journal of inclusion phenomena

, Volume 1, Issue 4, pp 365–368 | Cite as

Inclusion compounds formed between α,ω-(long-carbon-chain)-diaminecademium(II) tetracyanonickelate(II) host and aromatic guest molecules

  • Tai Hasegawa
  • Shin-Ichi Nishikiroi
  • Toschitake Iwamoto
Article

Abstract

Inclusion compounds with the general formula Cd(NH2(CH2) n NH2)Ni(CN)4·xG were prepared forn=4 to 8, and for G of such an aromatic guest molecule as pyrrole, benzene, aniline, toluene, toluidine, xylene, xylidine, dichlorobenzene, trimethylbenzene, tetramethylbenzene, ethylbenzene, styrene, or isopropylbenzene, with varyingx. Generally, longer chain lengths of α,ω-diamine in the host permit the inclusion of bulkier guest molecules. However, the presence of an amino group on the phenyl ring of the guest appears to impart a special affinity with the hosts.

Key words

Hofmann-type clathrate pyrrole benzene aniline substituted benzene substituted aniline 1,4-diaminobutane 1,5-diaminopentane 1,6-diaminohexane 1,7-diaminoheptane 1,8-diaminooctane cadmium tetracyanonickelate 

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Copyright information

© D. Reidel Publishing Company 1984

Authors and Affiliations

  • Tai Hasegawa
    • 1
  • Shin-Ichi Nishikiroi
    • 1
  • Toschitake Iwamoto
    • 1
  1. 1.Department of Chemistry, College of Arts and SciencesThe University of TokyoMeguro TokyoJapan

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