Abstract
In contrast top-hydroxyphenyl-2,2,4-trimethylchroman, Dianin's compound (1), or itsthia analogue2, the title seleno-ether has been found to form two crystallographically distinct types of clathrate. In the first-discovered form, the α-modification of as yet undefined structure, the rhombohedral unit cell (R\(\bar 3\), a = 57.42(1) Å, c = 10.817(1) Å, [from EtOH]) has approximately four times the volume of that found in the clathrates of1 or2 and contains 72 host molecules. Recrystallisation of the selena-host fromn-hexane, however, produces another type of rhombohedral crystal: theβ-modification has space group R\(\bar 3\), witha=28.225(2)Å,c=10.859(1)Å, and 18 host molecules in the unit cell. A detailed X-ray study of this latter inclusion compound (host-guest ratio 6:1) has established its true clathrate nature; the disorderedn-hexane guest, showing electron density consistent with an extended planar zig-zag conformation, is found threading the hour glass-shaped cavity's central constriction.
Similar content being viewed by others
References
For a review see, for example, D. D. MacNicol inInclusion Compounds (Eds. J. L. Atwood, J. E. D. Davies, and D. D. MacNicol), Academic Press, London, Vol. 2, Chapter 1. pp. 1–45 (1984).
J. L. Flippen, J. Karle, and I. L. Karle:J. Am. Chem. Soc. 92, 3749 (1970).
D. D. MacNicol, H. H. Mills, and F. B. Wilson.Chem. Commun. 1332 (1969).
B. S. Middleditch and D. D. MacNicol:Org. Mass. Spectrom. 11, 212 (1976).
MITHRIL, A Computer Program for the Automatic Solution of Crystal Structures from X-ray Data, C. J. Gilmore:J. Appl. Crystallogr. 17, 42 (1984);
The GX Crystallographic Program System, P. R. Mallinson and K. W. Muir:J. Appl. Crystallogr. 18, 51 (1985);
DIFABS Empirical Absorption Correction program, N. Walker and D. Stuart:Acta Crystallogr. A39, 158 (1983).
H. H. Mills, D. D. MacNicol, and F. B. Wilson: unpublished results.
D. D. MacNicol and F. B. Wilson:J. Chem. Soc., Chem. Commun. 786 (1971).
J. L. Flippen and J. Karle:J. Phys. Chem. 75, 3566 (1971).
N. Norman and H. Mathisen:Acta Chem. Scand. 15, 1755 (1961).
Author information
Authors and Affiliations
Additional information
Supplementary Data relating to this article are deposited with the British Library as Supplementary Publication No. SUP 82045 (25 pages).
Rights and permissions
About this article
Cite this article
MacNicol, D.D., Mallinson, P.R., Keates, R.A.B. et al. Crystal structure of theβ-clathrate form of 4-p-hydroxyphenyl-2,2,4-trimethylselenachroman. Journal of Inclusion Phenomena 5, 373–377 (1987). https://doi.org/10.1007/BF00665370
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00665370