Abstract
The intercalation of ferrocene and dimethylaminomethylferrocene into α-tin(IV) hydrogen phosphate (SnP) and α-vanadyl phosphate has been investigated. Successful intercalation of 0.81 mol of dimethylamino-methylferrocene into α-SnP by an acid-base reaction in aqueous medium to form a bilayer of protonated amines was achieved. However, ferrocene was not intercalated under the same conditions. Intercalation of α-vanadyl phosphate by 0.11 mol of ferrocene in acetonic medium at room temperature was effected by a redox topotactic reaction. The voluminous dimethylaminomethylferrocene was not intercalated into α-vanadyl phosphate.
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Rodríguez-Castellón, E., Jiménez-Ĺópez, A., Martínez-Lara, M. et al. Intercalation of ferrocene and dimethylaminomethylferrocene into α-Sn(HPO4)2 · H2O and α-VOPO4 · 2H2O. Journal of Inclusion Phenomena 5, 335–342 (1987). https://doi.org/10.1007/BF00665366
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DOI: https://doi.org/10.1007/BF00665366