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Microporous adsorbent sieve effect on thermodynamic functions for state of perturbation in adsorbed molecules

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Abstract

The correctness of the modified Polanyi-Dubinin potential theory application for the description of the thermodynamic state of polar molecules has been studied. It has been stated that the fundamental condition to obtain proper results is to include the influence of eventual molecular sieve effects. The values obtained for thermodynamic functions of perturbation determine the state of molecules only for those adsorbates for which the adsorption mechanism corresponds to the theory of volume filling of micropores.

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Authors and Affiliations

  1. Central Institute of Chemistry, N. Copernicus University, 87-100, Toruń, Poland

    Michał Rozwadowski & Roman Wojsz

Authors
  1. Michał Rozwadowski
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  2. Roman Wojsz
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Rozwadowski, M., Wojsz, R. Microporous adsorbent sieve effect on thermodynamic functions for state of perturbation in adsorbed molecules. Journal of Inclusion Phenomena 5, 297–305 (1987). https://doi.org/10.1007/BF00665362

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  • DOI: https://doi.org/10.1007/BF00665362

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