Abstract
Conductance measurements for fifteen uni-univalent salts in 2-methylpyridine-N-oxide (2-MPO) were made over the concentration range of 2−120×10−4 mol-dm−3 at 55°C. All conductance data were evaluated by the Lee-Wheaton equation. The results indicate that all of the salts studied are slightly associated in 2-MPO, which is, nevertheless, a reasonably good ionizing solvent compared to other solvents having a similar value for the dielectric constant. The tetraalkylammonium halides are weaker electrolytes than the tetraphenylborate salts in 2-MPO. Ionic limiting molar conductances were obtained by using as a reference electrolyte tris(iso-pentyl)butylammonium tetraphenylborate. Anions appear to be poorly solvated in this solvent but certain cations, particularly Na+ and K+, show evidence of specific ion-solvent interaction.
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References
J. F. Casteel and P. G. Sears,J. Chem. Eng. Data 19, 303 (1974).
H. L. Huffman, Jr., Ph.D. dissertation, University of Kentucky (1972).
B. J. Barker and P. G. Sears,J. Phys. Chem. 78, 2687 (1974).
R. M. Fuoss,J. Phys. Chem. 79, 525 (1975).
R. M. Fuoss,J. Am. Chem. Soc. 57, 2604 (1935).
W. H. Lee and R. J. Wheaton,J. Chem. Soc. Faraday II 75, 1128 (1979).
W. H. Lee and R. J. Wheaton,J. Chem. Soc. Faraday II 74, 743 (1978).
W. H. Lee and R. J. Wheaton,J. Chem. Soc. Faraday II 74, 1456 (1978).
A. D. Pethybridge and S. S. Taba,J. Chem. Soc. Faraday I 76, 368 (1980).
E. Grunwald, G. Baughman, and G. Kohnstam,J. Am. Chem. Soc. 82, 5801 (1960).
R. A. Robinson and R. H., Stokes,Electrolyte Solutions, 2nd edn. rev. Butterworths, London, 1965); pp 124–125, 461.
R. L. Kay, C. Zawoyski, and D. F. Evans,J. Phys. Chem. 69, 4208 (1965).
E. Hirsch and R. M. Fuoss,J. Amer. Chem. Soc. 82, 1018 (1960).
D. F. Evans, C. Zawoyski, and R. L. Kay,J. Phys. Chem. 69, 3878 (1965).
P. G. Sears, E. D. Wilhoit, and L. R. Dawson,J. Phys. Chem. 59, 373 (1955) and unpublished data.
R. P. De Sieno, P. W. Greco, and R. C. Mamajek,J. Phys. Chem. 75, 1722 (1971).
G. Petrella, M. Castagnolo, A. Sacco, and A. De Giglio,J. Solution Chem. 5, 621 (1976).
P. G. Sears, G. R. Lester, and L. R. Dawson,J. Phys. Chem. 60, 1433 (1956).
R. Fernández-Prini and G. Urrutia,J. Chem. Soc. Faraday I 72, 637 (1976).
M. A. Coplan and R. M. Fuoss,J. Phys. Chem. 68, 1177 (1964).
G. Petrella, A. Sacco, M. Castagnolo, M. Della Monica, and A. De Giglio,J. Solution Chem. 6, 13 (1977).
R. L. Kay inWater: A Comprehensive Treatise, Vol. 3, F. Franks, ed. (Plenum Press, New York, 1973), Chap. 4.
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Casteel, J.F., Lemire, R.J. & Sears, P.G. Conductances of some electrolytes in 2-methylpyridine-N-oxide at 55°C. J Solution Chem 11, 55–62 (1982). https://doi.org/10.1007/BF00664334
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DOI: https://doi.org/10.1007/BF00664334