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The crystal structures of α,ω-diaminoalkanecadmium(II) tetracyanonickelate(II)-aromatic molecule inclusion compounds. I. 1,4-diaminobutanecadmium(II) tetracyanonickelate(II)-2,5-xylidine (1/1): Cd(NH2(CH2)4NH2)Ni(CN)4. (CH3)2C6H3NH2

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Abstract

The title compound crystallizes in monoclinic space group P21/m with a=9.795(2), b=15.010(2), c=7.125(1) Å, β=105.56(1)o, and Z=2. The structure has been refined to the weighted Rw=0.042 for 2742 reflections collected by counter method. Two-dimensionally extended but wavy cyanometal complex layers are bridged by 1,4-diaminobutane (dabn) to give a three-dimensional host structure which provides a channel-like cavity with the guest 2,5-xylidine molecule. The skeleton of the bridging dabn takes a trans-cis conformation to make the packing efficient between the cavity and the guest molecule. The series of Hofmann-dabn-type Cd(NH2 (CH2)4NH2) Ni (CN)4. nG inclusion compounds are described for several aromatic guest molecules G with various stoichiometric coefficients n.

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Authors and Affiliations

  1. Department of Chemistry, College of Arts and Sciences, The University of Tokyo, Komaba, Meguro, 153, Tokyo, Japan

    Shin-ichi Nishikiori & Toschitake Iwamoto

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  1. Shin-ichi Nishikiori
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  2. Toschitake Iwamoto
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Supplementary Data relating to this article are deposited with the British Library as Supplementary Publication No. SUP 82020 (22 pages).

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Nishikiori, Si., Iwamoto, T. The crystal structures of α,ω-diaminoalkanecadmium(II) tetracyanonickelate(II)-aromatic molecule inclusion compounds. I. 1,4-diaminobutanecadmium(II) tetracyanonickelate(II)-2,5-xylidine (1/1): Cd(NH2(CH2)4NH2)Ni(CN)4. (CH3)2C6H3NH2 . Journal of Inclusion Phenomena 2, 341–349 (1984). https://doi.org/10.1007/BF00663274

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