Abstract
Isopiestic measurements have been made on NaCl−SrCl2 mixtures at 25°C over the ionic strength range 0.6–6 mole-kg−1. The results are interpreted in terms of current mixed-electrolyte treatments. The mixing behavior in this system is comparatively simple, but the Pitzer treatment is still clearly superior to the other treatments.
Similar content being viewed by others
References
J. B. Macaskill, M. S. Mohan, and R. G. Bates,Anal. Chem. 49, 209 (1977).
R. A. Robinson and R. H. Stokes,Electrolyte Solutions, 2nd rev. ed. (Butterworths, London, 1970).
R. A. Robinson,Trans. Faraday Soc. 36, 735 (1940).
R. H. Stokes,Trans. Faraday Soc. 44, 295 (1948).
C. J. Downes,J. Chem. Thermodyn. 6, 317 (1974).
R. M. Rush and J. S. Johnson,J. Phys. Chem. 72, 767 (1968).
K. S. Pitzer,J. Phys. Chem. 77, 268 (1973).
K. S. Pitzer and J. J. Kim,J. Am. Chem. Soc. 96, 5701 (1974).
G. Scatchard,J. Am. Chem. Soc. 83, 2636 (1961).
G. Scatchard, R. M. Rush, and J. S. Johnson,J. Phys. Chem. 74, 3786 (1970).
P. J. Reilly, R. H. Wood, and R. A. Robinson,J. Phys. Chem. 75, 1305 (1971).
R. A. Robinson and V. E. Bower,J. Res. Nat. Bur. Stand. Sect. A. 70, 313 (1966).
R. M. Rush,Oak Ridge Nat. Lab. Rept. ORNL-4402 (1969).
C. J. Downes,J. Solution Chem. 4, 191 (1975).
G. Scatchard, R. M. Rush, and J. S. Johnson,J. Phys. Chem. 74, 3786 (1970), Table VII.
K. S. Pitzer,J. Phys. Chem. 77, 268 (1973), Table III.
Y. C. Wu, R. M. Rush, and G. Scatchard,J. Phys. Chem. 73, 2047 (1969).
Y. C. Wu, R. M. Rush, and G. Scatchard,J. Phys. Chem. 72, 4048 (1968).
R. A. Robinson and V. E. Bower,J. Res. Nat. Bur. Stand. Sect. A 69, 19 (1965).
J. Padova and D. Saad,J. Solution Chem. 6, 57 (1977).
R. A. Robinson and A. K. Covington,J. Res. Nat. Bur. Stand. Sect. A 72, 239 (1968).
R. A. Robinson and V. E. Bower,J. Res. Nat. Bur. Stand. Sect. A 69, 439 (1965).
S. Lindenbaum, R. M. Rush, and R. A. Robinson,J. Chem. Thermodyn. 4, 381 (1972).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Macaskill, J.B., White, D.R., Robinson, R.A. et al. Isopiestic measurements on aqueous mixtures of sodium chloride and strontium chloride. J Solution Chem 7, 339–347 (1978). https://doi.org/10.1007/BF00662894
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00662894