Skip to main content
Log in

Relaxation processes in polyatomic molecular vapors using infrared absorption bands

  • Published:
Journal of Applied Spectroscopy Aims and scope

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Literature cited

  1. R. G. Gordon, "On the rotational diffusion of molecules,"J. Chem. Phys.,44, No. 5, 1830–1836 (1966).

    Google Scholar 

  2. St. A. G. Pierre and W. A. Steele, "Time correlations and conditional distribution function for classical ensembles of free rotors,"Phys. Rev.,184, No. 1, 172–186 (1969).

    Google Scholar 

  3. R. E. D. McClung, "On the extended rotational diffusion models for molecular reorientation in fluids,"Adv. Mol. Relax. Processes,10, No. 2, 83–170 (1977).

    Google Scholar 

  4. G. Herzberg, Vibrational and Rotational Spectra of Polyatomic Molecules [Russian translation], IL, Moscow (1949); H. C. Allen and P. C. Cross, Molecular Vibrotor, New York (1963).

    Google Scholar 

  5. A. I. Burshtein and S. I. Temkin, "Collapse of the rotational structure of Raman scattering spectra in dense media,"Zh. Eksp. Toer. Fiz.,71, No. 9, 938–951 (1976); V. A. Alekseev and A. V. Malyugin, "General features of collisional narrowing of spectral lines in gases,"Zh. Eksp. Teor. Fiz.,80, No. 3, 897–915 (1981).

    Google Scholar 

  6. R. G. Bray and M. Z. Berry, "Intramolecular rate processes in highly vibrationally excited benzene," J. Chem. Phys.,71, No. 12, 4909–4922 (1979); R. Henry and Ali Mohammadi, "Bandwidths in the gas phase overtone spectra of neopentane,"Chem. Phys. Lett.,75, No. 1, 99–103 (1980); G. A. West, R. P. Mariella, J. A. Pete, et al., "Ultrafast intramolecular vibrational relaxation: The overtone spectrum of supercooled tetramethyldioxetane,"J. Chem. Phys.,75, No. 4, 2006–2007 (1981).

    Google Scholar 

  7. B. F. Gordiets, A. I. Osipov, E. V. Stupochenko, and L. A. Shelepin, "Vibrational relaxation in gases and molecular lasers,"Usp. Fiz. Nauk,108, No. 4, 655–699 (1972).

    Google Scholar 

  8. K. F. Freed and A. Nitran, "Intramolecular vibrational energy redistribution and the time evolution of molecular fluorescence,"J. Chem. Phys.,73, No. 10, 4765–4778 (1980).

    Google Scholar 

  9. N. A. Borisevich, G. A. Zalesskaya, and T. Shukurov, "Effect of foreign gases on rotational motion of chloroform molecules,"Dokl. Akad. Nauk BSSR,22, No. 7, 659–662 (1978).

    Google Scholar 

  10. N. A. Borisevich, G. A. Zalesskaya, and T. Shukurov, "Rotational motion of bromoform molecules at high foreign-gas pressures,"Zh. Prikl. Spektrosk.,34, No. 1, 137–143 (1981).

    Google Scholar 

  11. G. A. Zalesskaya and T. Shukurov, "Effect of foreign gases on the perpendicular absorption band of the chloroform molecule,"Dokl. Akad. Nauk BSSR,26, No. 3, 228–231 (1982).

    Google Scholar 

  12. T. Shukurov, "Investigation of rotational motion of trichloroethylene in compressed gases using the IR absorption band contours,"Izv. Akad. Nauk BSSR, Ser. Fiz-Mat., No. 3, 84–87 (1981).

    Google Scholar 

  13. N. A. Borisevich and G. A. Zalesskaya, "Investigation of the characteristics of the formation of infrared absorption bands of polyatomic molecular vapors,"Opt. Spektrosk.,37, No. 1, 72–77 (1974).

    Google Scholar 

  14. G. A. Zalesskaya and V. A. Lastochkina, "Study of the rotational motion of polyatomic molecules in vapors using the infrared absorption band contours,"Opt. Spektrosk.,37, No. 5, 875–881 (1974).

    Google Scholar 

  15. R. E. D. McClung, "Rotational diffusion of symmetric top molecules in liquids,"J. Chem. Phys.,57, 5478–5491 (1972).

    Google Scholar 

  16. St. A. G. Pierre and W. A. Steele, "Collisional effects upon rotational correlations of symmetric top molecules,"J. Chem. Phys.,57, 4638–4648 (1972).

    Google Scholar 

  17. K. Müller and F. Kneubühe, "Influence of the coriolis coupling on angular correlation functions of rotating molecules,"Chem. Phys.,8, 468–481 (1975).

    Google Scholar 

  18. J. M. Hollas, "Computed band envelopes for electronic and vibrational spectra of large symmetric top molecules," Spectrochim. Acta,22, 81–93 (1966).

    Google Scholar 

  19. M. L. Bonsal and A. P. Roy, "A study of the rotational correlation function for cyclohexane by Raman scattering,"Mol. Phys.,38, 1419–1426 (1979).

    Google Scholar 

  20. M. L. Sage and J. Jortner, "Resonance structure and background absorption in high overtone molecular spectra,"Chem. Phys. Lett.,62, No. 3, 451–456 (1979).

    Google Scholar 

  21. P. J. Robinson and K. A. Holbrook, Unimolecular Reactions, Wiley (1972).

  22. J. Soussen-Jacob, E. Dervil, and J. Vincent-Geisse,"Etude de mouvements moleculaires en milieu liquide á partir du profil des bands de vibration dans l'infrarouge et des fonctions de corrélation. III. Chloroforme et bromoforme,"Mol. Phys.,28, No. 24, 935–955 (1974).

    Google Scholar 

  23. G. A. Zalesskaya and V. A. Lastochkina, "Effect of nonpolar solvents on infrared absorption bands of naphthalene,"Opt. Spektrosk.,44, 504–509 (1978).

    Google Scholar 

  24. G. A. Zalesskaya and V. A. Lastochkina, "Investigation of the vibrational relaxation of naphthalene molecules in nonpolar solvents using the Raman scattering spectra,"Opt. Spektrosk.,47, 306–309 (1979).

    Google Scholar 

  25. N. G. Bakhshiev and P. I. Zelikman, "Mechanisms of broadening of bands in vibrational spectra of liquid systems,"Dokl. Akad. Nauk SSSR,250, No. 1, 128–132 (1980).

    Google Scholar 

Download references

Authors

Additional information

Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 37, No. 6, pp. 896–906, December, 1982.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Borisevich, N.A., Zalesskaya, G.A. & Shukurov, T. Relaxation processes in polyatomic molecular vapors using infrared absorption bands. J Appl Spectrosc 37, 1337–1346 (1982). https://doi.org/10.1007/BF00662476

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00662476

Keywords

Navigation