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Synthesis of two regiospecific isomers of monotosyl-γ-cyclodextrin

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Abstract

Tosylation of γ-cyclodextrin in an aqueous alkaline solution gave two regiospecific isomers (2-monotosyl-γ-cyclodextrin(1) and 6-monotosyl-γ-cyclodextrin(2)), that could recognize and catalyze small sized guest molecules; 2-monotosyl-γ-CD recognized small sized guest molecules more effectively than did 6-monotosyl-γ-CD.

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Takahashi, K., Hattori, K. Synthesis of two regiospecific isomers of monotosyl-γ-cyclodextrin. Journal of Inclusion Phenomena 2, 661–667 (1984). https://doi.org/10.1007/BF00662233

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