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On the orthorhombic phase in ZrO2-based alloys

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Abstract

During TEM observation, a tetragonal (t) to orthorhombic (o) phase transformation often occurs in thin portions of ZrO2-containing foils. This transformation is stress-induced and in some senses artefactual, in that the reaction product is actually a high-pressure phase, relative to monoclinic (m) ZrO2, that can form from metastable t-ZrO2 in the TEM because its density is intermediate between t- and m-ZrO2. Examples of the formation of o-ZrO2 in a number of different systems are given.

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References

  1. J. D. McCullough andK. N. Trueblood,Acta Crystallogr. 12 (1959) 507.

    Google Scholar 

  2. L. N. Komissarova, Yu. P. Simanov andZ. A. Vladimirova,Russ. J. Inorg. Chem. 5 (1960) 687.

    Google Scholar 

  3. G. Teufer,Acta Crystallogr. 15 (1962) 1187.

    Google Scholar 

  4. D. K. Smith andH. W. Newkirk,ibid. 18 (1965) 983.

    Google Scholar 

  5. G. Katz,J. Amer. Ceram. Soc. 54 (10) (1971) 531.

    Google Scholar 

  6. P. Aldebert andJ. P. Traverse,ibid. 68 (1) (1985) 34.

    Google Scholar 

  7. R. E. Hann, P. R. Svitch andJ. L. Pentecost,ibid. 68 (10) (1985) C285.

    Google Scholar 

  8. H. G. Scott,J. Mater. Sci. 10 (1975) 1527.

    Google Scholar 

  9. R. A. Miller, J. L. Smialek andR. G. Garlick, in “Advances in Ceramics”, Vol. 3, edited by A. H. Heuer and L. W. Hobbs (American Ceramic Society, Columbus, Ohio, 1981) p. 241.

    Google Scholar 

  10. D. Michel, L. Mazerolles andM. Perez yJorba,J. Mater. Sci. 18 (1983) 2618.

    Google Scholar 

  11. V. Lanteri, T. E. Mitchell andA. H. Heuer, in “Advances in Ceramics”, Vol. 12, edited by N. Claussen, M. Ruhle and A. H. Heuer (American Ceramic Society, Columbus, Ohio, 1984) p. 118.

    Google Scholar 

  12. R. Chaim, M. Ruhle andA. H. Heuer,J. Amer. Ceram. Soc. 68 (8) (1985) 427.

    Google Scholar 

  13. A. H. Heuer, R. Chaim andV. Lanteri,Acta Metall. 3 (1987) 661.

    Google Scholar 

  14. A. H. Heuer andL. W. Hobbs (eds), “Advances in Ceramics”, Vol. 3 (American Ceramic Society, Columbus, Ohio, 1981).

    Google Scholar 

  15. N. Claussen, M. Ruhle andA. H. Heuer (eds), “Advances in Ceramics”, Vol.12 (American Ceramic Society, Columbus, Ohio, 1984).

    Google Scholar 

  16. H. Hasewaga,J. Mater. Sci. Lett. 2 (1983) 91.

    Google Scholar 

  17. H. Hasewaga, T. Hioki andO. Kamigaito,ibid. 4 (1985) 1092.

    Google Scholar 

  18. N. A. Bendeliani, S. V. Popova andL. P. Verschagin,Geokhimiya 6 (1967) 677.

    Google Scholar 

  19. G. Bocquillon andC. Susse,Rev. Int. Hautes Temp. Refract. 6 (1969) 263.

    Google Scholar 

  20. L. G. Liu,J. Phys. Chem. Solids 41 (1980) 331.

    Google Scholar 

  21. S. Block, J. A. H. DaJornada andG. J. Piermarini,J. Amer. Ceram. Soc. 68 (9) (1985) 497.

    Google Scholar 

  22. R. Suyama, T. Ashida andS. Kume,ibid. 68 (12) (1985) C314.

    Google Scholar 

  23. Y. Kudoh, H. Takeda andH. Arashi,Phys. Chem. Miner. 13 (1986) 233.

    Google Scholar 

  24. L. Lenz andA. H. Heuer,J. Amer. Ceram. Soc. 65 (11) (1982) C192.

    Google Scholar 

  25. L. H. Schoenlein andA. H. Heuer, in “Fracture Mechanics of Ceramics”, Vol. 6, edited by R. C. Bradt, A. G. Evans, D. P. H. Hasselman and F. F. Lange (Plenum, New York, 1983) pp. 309–323.

    Google Scholar 

  26. A. H. Heuer andL. H. Schoenlein,J. Mater. Sci. 20 (1985) 3421.

    Google Scholar 

  27. A. H. Heuer, L. H. Schoenlein andS. C. Farmer, “Science of Ceramics 12” (Ceramurgica, Faenza, Italy, 1983) pp. 257–266.

    Google Scholar 

  28. L. H. Schoenlein, PhD thesis, Case Western Reserve University (1982).

  29. B. C. Muddle, in “Advanced Structural Ceramics”, edited by P. F. Becher, M. V. Swain and S. Somiya, Material Research Symposium Proceedings Vol.78 (1987) 3.

  30. T. A. Bielicki, H. Dahmen, G. Thomas andK. H. Westmacott, in Proceedings of “ZrO2 '86”, in “Advances in Ceramics”, Vol. 24, edited by S. Somiya, N. Yamamoto and H. Yanagida (American Ceramic Society, Columbus, Ohio, 1988) in press.

    Google Scholar 

  31. Y. H. Chiao andI-Wei Chen, in “Grain Boundary Structure and Related Phenomena”, Proceedings of JIMIS No. 4,Trans. Jap. Inst. Metals 27 (Suppl.) (1986) 197–203.

    Google Scholar 

  32. R. M. Dickerson, M. Swain andA. H. Heuer,J. Amer. Ceram. Soc. 70 (4) (1987) 214.

    Google Scholar 

  33. A. H. Heuer, R. Chaim, andV. Lanteri in Proceedings of “ZrO2 '86”, in “Advances in Ceramics”, Vol. 24, edited by S. Somiya, N. Yamamoto and H. Yanagida (American Ceramic Society, Columbus, Ohio, 1988) in press.

    Google Scholar 

  34. H. Bestgen, R. Chaim andA. H. Heuer,J. Amer. Ceram. Soc. in press.

  35. R.-R. Lee andA. H. Heuer,ibid. 71 (8) (1988) 694–700.

    Google Scholar 

  36. D. B. Marshall, M. James andR. J. Paster,ibid. (in press).

    Google Scholar 

  37. H. Arashi, in Proceedings of “ZrO2 '86”, in “Advances in Ceramics”, Vol. 24, edited by S. Somiya, N. Yamamoto and H. Yanagida (American Ceramic Society, Columbus, Ohio, 1988) in press.

    Google Scholar 

  38. V. Lanteri, T. E. Mitchell andA. H. Heuer,J. Amer. Ceram. Soc. 69 (7) (1986) 564.

    Google Scholar 

  39. N. Ishizawa, A. Saiki, J. Jogi, N. Mizutani andM. Kato,ibid. 69 (2) (1986) C18.

    Google Scholar 

  40. M. Shibata-Yanagisawa, M. Kato, H. Seto, N. Ishizawa, N. Mizutani andM. Kato,ibid. 70 (7) (1987) 505.

    Google Scholar 

  41. A. H. Heuer, V. Lanteri andR. Chaim,Ultramicrosc. 22 (1987) 27.

    Google Scholar 

  42. J. M. Marder, T. E. Mitchell andA. H. Heuer,Acta. Metall. 31 (1983) 387.

    Google Scholar 

  43. R.-R. Lee andA. H. Heuer,J. Amer. Ceram. Soc. 70 (4) (1987) 208.

    Google Scholar 

  44. B. W. Kibbel andA. H. Heuer, to be published.

  45. M. A. O'Keefe andP. R. Buseck,Trans. Amer. Crystallogr. Assoc. 15 (1) (1979) 27.

    Google Scholar 

  46. M. Cohen, G. B. Olsen andP. C. Clapp, in Proceedings of International Conference on Martensitic Transformations, Cambridge, Massachusetts, 1979, p. 1.

  47. G. Van Tendeloo andS. Amelinckx,Acta Crystallogr. A30 (1974) 431.

    Google Scholar 

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Authors and Affiliations

  1. Department of Materials Science and Engineering, Case Western Reserve University, 44106, Cleveland, Ohio, USA

    A. H. Heuer, V. Lanteri, S. C. Farmer, R. Chaim, R. R. Lee, B. W. Kibbel & R. M. Dickerson

  2. IRSID, St. Germain en Laye, France

    V. Lanteri

  3. NASA Lewis Research Center, Cleveland, Ohio

    S. C. Farmer

  4. Technion, Haifa, Israel

    R. Chaim

  5. CPS, Inc., Cambridge, Massachusetts

    R. R. Lee

  6. General Motors Research Laboratory, Detroit, Michigan

    B. W. Kibbel

Authors
  1. A. H. Heuer
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  2. V. Lanteri
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  3. S. C. Farmer
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  4. R. Chaim
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  5. R. R. Lee
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  6. B. W. Kibbel
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  7. R. M. Dickerson
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Heuer, A.H., Lanteri, V., Farmer, S.C. et al. On the orthorhombic phase in ZrO2-based alloys. J Mater Sci 24, 124–132 (1989). https://doi.org/10.1007/BF00660943

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  • DOI: https://doi.org/10.1007/BF00660943

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