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Crystal structure of 1-methyl-1,3,5,7-tetraazaadamantan-1-ium ammonium sulfate hydrate, a double salt containing puckered layers of hydrogen-bonded NH +4 and SO 2−4 groups

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Abstract

The double salt [(CH2)6N4CH3](NH4)SO4·H2O crystallizes in space groupP21/a, witha=12.994(2),b=6.319(1),c=15.082(2) Å, β=93.78(2)o, andZ=4. The structure was solved by the heavy-atom method and refined toR F 2=0.051 for 2478 MoKα data. The ammonium and sulfate ions are cross-linked by hydrogen bonds to form puckered layers disposed about the (001) family of planes. Each water molecule bridges a [(CH2)6N4CH3]+ ion and a sulfate group, so that the organic cations lying on both sides of a puckered layer have their methyl groups pointing inward and fitting into depressions.

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Authors and Affiliations

  1. Department of Chemistry, Brookhaven National Laboratory, 11973, Upton, NY, USA

    Richard K. McMullan

  2. Department of Chemistry, The University of Kansas, 66045, Lawrence, KA, USA

    Fusao Takusagawa

  3. Department of Chemistry, The Chinese University of Hong Kong, Shatin New Territories, Hong Kong

    Thomas C. W. Mak

Authors
  1. Richard K. McMullan
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  2. Fusao Takusagawa
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  3. Thomas C. W. Mak
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Additional information

Supplementary Data relating to this article are deposited with the British Library as Supplementary Publication No. SUP 82063 (18 pages).

Carried out, in part, under contract DE-AC02-76CH00016 with the U.S. Department of Energy, Office of Basic Energy Sciences.

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McMullan, R.K., Takusagawa, F. & Mak, T.C.W. Crystal structure of 1-methyl-1,3,5,7-tetraazaadamantan-1-ium ammonium sulfate hydrate, a double salt containing puckered layers of hydrogen-bonded NH +4 and SO 2−4 groups. Journal of Inclusion Phenomena 6, 515–521 (1988). https://doi.org/10.1007/BF00660749

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  • DOI: https://doi.org/10.1007/BF00660749

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