Abstract
Barium ethyl(alkyl)phosphates, as new simple surfactants ((C2H5O)(RO)-PO −2 )2Ba2+ with various chain length ofR, were synthesized. The infrared spectra in the CH stretching region were measured for these surfactants in the solid state and in aqueous solution, and assignments were made. In particular, the ordering and environment of octyl chains in the different phases of the barium ethyl(octyl)phosphate-water system were studied by the Fourier-transform-infrared and Raman spectra. The CH stretching bands in the infrared spectra reflected the ordering and environment of octyl chains in each phase. The Raman band connected to the PO −2 symmetric stretching mode was sensitively shifted. This was caused by the change of aggregation structures with different Ba2+...PO −2 interaction. The infrared band arising from the PO −2 antisymmetric stretching mode was insensitive to the phase structures. The C−C stretching region in the infrared spectra was used to discuss the ordering of each phase.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Brown KG, Peticolas WL, Brown E (1972) Biochem Biophys Res Commun 54:358–368
Gaber BP, Peticolas WL (1977) Biochim Biophys Acta 465:260–274
Larsson K, Rand RP (1973) Biochim, Biophys Acta 326:245–255
Bulkin BJ, Krishnamachari NJ (1972) J Am Chem Soc 94:1109–1112
Spiker RC Jr, Levin IW (1975) Biochim Biophys Acta 388:361–373
Faiman R, Larsson K (1976) J Raman Spectrosc 4:387–394
Mendelsohn R, Sunder S, Bernstein HJ (1976) Biochim Biophys Acta 419:563–569
Verma SP, Wallach DFH (1977) Biochem Biophys Res Commun 74:473–479
Lippert JL, Peticolas WL (1971) Proc Natl Acad Sci 68:1572–1576
Brown KG, Bicknell-Brown E, Ladjadj M (1987) J Phys Chem 91:3436–3442
Lis LJ, Kauffman JW, Shriver DF (1976) Biochim Biophys Acta 436:513–522
Zerbi G, Conti G, Minoni G, Pison S, Bigotto A (1987) J Phys Chem 91:2386–2393
Kim Y, Strauss HL, Snyder RG (1988) J Phys Chem 92:5080–5082
Hui YW, Labes MM (1987) J Phys Chem 91:6066–6069
Okabayashi H, Okuyama M, Kitagawa T (1975) Bull Chem Soc Japan 48:2264–2269
Rosenholm JB, Stenius P, Danielsson I (1976) J Colloid Interface Sci 57:551–563
Umemura J, Cameron DG, Mantsch HH (1980) Biochim Biophys Acta 602:32–44
Umemura J, Mantsch HH, Cameron DG (1981) J Colloid Interface Sci 83:558–568
Cameron DG, Umemura J, Wong PTT, Mantsch HH (1982) Colloids Surfaces 4:131–145
Kawai T, Umemura J, Takenaka T, Kodama M, Seki S (1985) J Colloid Interface Sci 103:56–61
Dluhy RA, Chowdhry BZ, Cameron DG (1985) Biochim Biophys Acta 821:437–443
Holmgren A, Fontell, Krister F, Lindblom G (1986) Acta Chem Scand A40:299–305
Casal HL (1988) J Am Chem Soc 110:5203–5205
Miyagai K, Yoshida T, Aoki S, Taga K, Okabayashi H, to be submitted
Zervas L, Dilaris I (1955) J Am Chem Soc. 77:5354–5357
Mukaiyama T, Fujisawa T (1961) Bull Chem Soc Japan 34:812–813
Okabayashi H, Kitagawa T (1987) J Phys Chem 82:1830–1936
Mantsch HH (1984) J Mol Struct 113:201–212
Okabayashi H, Yoshida T, Ikeda T, Matsuura H, Kitagawa T (1982) J Am Chem Soc. 104:5399–5402
Snyder RG, Schachtschneider JH (1963) Spectrochim Acta 19:85–116
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Miyagai, K., Taga, K., Yoshida, T. et al. Infrared and raman studies on the phase structure of barium ethyl(octyl)phosphate-water system. Colloid Polym Sci 269, 153–160 (1991). https://doi.org/10.1007/BF00660305
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00660305