Skip to main content
Log in

Another look at the melting temperature of colloidal crystals in the completely deionized suspension

  • Original Contributions
  • Published:
Colloid and Polymer Science Aims and scope Submit manuscript

Abstract

Melting temperature (T m) of colloidal crystals of monodispersed polystyrene and silica spheres has been measured for thecompletely deionized suspensions as a function of sphere concentration. More than 3 weeks are needed before achievement of the completely deionized state.T mincreases substantially as the deionization process of the suspension proceeds. The most reliable values ofT mobserved for the completely deionized suspensions are successfully analyzed again with the theory of Williams et al. The newT mvalues are compared also with the theory of Robbins et al., which treats the repulsive Yukawa potential between colloidal spheres.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Williams R, Crandall RS, Wojtowicz PJ (1976) Phys Rev Lett 37:348

    Google Scholar 

  2. Okubo T (1991) J Chem Phys 95:3690

    Google Scholar 

  3. Okubo T (1992) J Chem Phys 96:2261

    Google Scholar 

  4. Okubo T (1992) Colloid Polym Sci 270:1018

    Google Scholar 

  5. Okubo T (1992) Naturwissenschaften 79:317

    Google Scholar 

  6. Okubo T (1992) Ber Bunsenges Phys Chem 96:61

    Google Scholar 

  7. Okubo T (1993) Colloid Polym Sci 271:190

    Google Scholar 

  8. Okubo T (1992) J Colloid Interface Sci 153:587

    Google Scholar 

  9. Kremer K, Robbins MO, Grest GS (1986) Phys Rev Lett 57:2694

    Google Scholar 

  10. Robbins MO, Kremer K, Grest GS (1988) J Chem Phys 88:3286

    Google Scholar 

  11. Vanderhoff W, van de Hul HJ, Tausk RJM, Overbeek J. ThG (1970) In: Goldfinger G (ed) Clean Surfaces: Their Preparation and Characterization for Interfacial Studies. Dekker, New York

    Google Scholar 

  12. Schaefer DW (1977) J Chem Phys 66:3980

    Google Scholar 

  13. Alexander S, Chaikin PM, Grant P, Morales GJ, Pincus P, Hone D (1984) J Chem Phys 80:5776

    Google Scholar 

  14. Okubo T (1987) Ber Bunsenges Phys Chem 91:1064

    Google Scholar 

  15. Okubo T (1988) J Colloid Interface Sci 125:380

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Okubo, T. Another look at the melting temperature of colloidal crystals in the completely deionized suspension. Colloid Polym Sci 272, 440–446 (1994). https://doi.org/10.1007/BF00659457

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00659457

Key words

Navigation