Abstract
Complexes of deoxycholic acid with polyethers, [−(CH2) m−1CHR−O−] n (R=H,m=2–4, 6 andR=CH3,m=2), were prepared. The crystals are orthorhombic and similar to those most commonly observed for complexes with low molecular weight molecules. Dimensiona in the poly(propylene oxide) complex is about 1 Å longer than those in other polyether complexes, whileb andc do not differ much in these DCA-polyether complexes.
Similar content being viewed by others
References
K. Takemoto and M. Miyata:J. Macromol. Sci., Rev. Macromol. Chem. C18, 83 (1980).
K. Suehiro, A. Urabe, Y. Yoshitake, and Y. Nagano:Makromol. Chem. 185, 2467 (1984).
K. Suehiro and Y. Nagano:Makromol. Chem. 184, 669 (1983).
E. Giglio:Inclusion Compounds of Deoxycholic Acid (Inclusion Compounds v. 2, Ed. J. L. Atwood, J. E. D. Davies, and D. D. MacNicol), pp. 207–229. Academic Press (1984).
B. M. Craven and G. T. De Titta:J. Chem. Soc. Chem. Commun. 530 (1972).
V. M. Coiro, A. D'Andrea, and E. Giglio:Acta Crystallogr. B36, 848 (1980).
J. G. Jones, S. Schwarzbaum, and L. Lessinger:Acta Crystallogr. B38, 1207 (1982).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Suehiro, K. Structural studies on molecular complexes of polyethers. 4 Deoxycholic acid-polyether complexes. Journal of Inclusion Phenomena 6, 9–13 (1988). https://doi.org/10.1007/BF00659364
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00659364