Abstract
Organic onium salts (3–15) are prepared and their inclusion capacity towards solvent molecules is investigated. The crystal structure of the1·propanol·H2O clathrate ofN,N′-[5-tert-butyl-1,3-phenylenebis(methylene)]bis(quinuclidinium)dibromide (4) is reported and compared with the X-ray structures of related clathrates described earlier.
Similar content being viewed by others
References
H.-G. Löhr, H.-P. Josel, A. Engel, F. Vögtle, W. Schuh, and H. Puff,Chem. Ber. 117, 1487 (1984).
F. Vögtle, H.-G. Löhr, H. Puff, and W. Schuh,Angew. Chem. 95, 425 (1983);Angew. Chem., Int. Ed. Engl. 22, 409 (1983);Angew. Chem. Suppl. 1983, 527–536.
H.-G. Löhr, F. Vögtle, W. Schuh, and H. Puff,J. Chem. Soc. Chem. Commun. 1983, 924.
H.-G. Löhr, F. Vögtle, W. Schuh, and H. Puff,J. Incl. Phenom. 1, 175 (1983).
P. Main, S. J. Fiske, S. E. Hull, L. Lessinger, G. Germain, J. P. Declerq, and M. M. Woolfson, MULTAN 80: A system of computer programs for the automatic solution of crystal structures from X-ray diffraction data, York, 1980.
G. M. Sheldrick, SHELX 76: Program for Crystal Structure Determination, Cambridge, 1976.
Author information
Authors and Affiliations
Additional information
Supplementary Data: Details of the crystal structure are available on request from the Fachinformationszentrum Energie-Physik-Mathematik, D-7517 Eggenstein, Leopoldshafen 2, by quoting the depository number CSD 50883, the names of the authors, and the journal citation.
Rights and permissions
About this article
Cite this article
Josel, HP., Löhr, HG., Engel, A. et al. Clathrates of organic onium halides, V: preparation of new clathrates and structure of the 1-propanol inclusion of a bis-quinuclidinium salt. Journal of Inclusion Phenomena 3, 43–50 (1985). https://doi.org/10.1007/BF00658860
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00658860