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Molecular inclusion in functionalized macrocycles part 10*: Crystal and molecular structure of ap-tert-butylcalix[6]arene hexapodand

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Abstract

Colourless prismatic crystals of (3) were obtained from ethanol/CH2Cl2 (1:1) solution, space groupP21/c,a=14.581(5),b=22.517(8),c=11.799(5) Å, β=92.13(4)°. Refinement led to a final conventionalR value of 0.074 for 4247 reflections. The conformation of the molecule, which lies on a center of symmetry, is 1,2,3-alternate with one oligoethereal chain pointing inside the molecular cavity.

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Authors and Affiliations

  1. Istituto di Chimica Organica dell'Università di Parma, Via M. D'Azeglio 85, 43100, Parma, Italy

    Rocco Ungaro & Andrea Pochini

  2. Centro di Studio per la Strutturistica Diffrattometrica del C.N.R., Istituto di Strutturistica Chimica dell'Università di Parma, Via M. D'Azeglio 85, 43100, Parma, Italy

    Giovanni Dario Andreetti & Paolo Domiano

Authors
  1. Rocco Ungaro
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  2. Andrea Pochini
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  3. Giovanni Dario Andreetti
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  4. Paolo Domiano
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Additional information

Supplementary Data relating to this article are deposited with the British Library as Supplementary Publication No. 82011 (30 pages).

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Ungaro, R., Pochini, A., Andreetti, G.D. et al. Molecular inclusion in functionalized macrocycles part 10*: Crystal and molecular structure of ap-tert-butylcalix[6]arene hexapodand. Journal of Inclusion Phenomena 3, 35–42 (1985). https://doi.org/10.1007/BF00658859

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  • DOI: https://doi.org/10.1007/BF00658859

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