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A study of association by hydrogen bonding in the system phenol-CCl4 by the nuclear magnetic relaxation method

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Abstract

The system phenol-CCl4 was studied by measuring proton and deuteron magnetic relaxation rates and self-diffusion coefficients at 25°C. From these data intermolecular relaxation rates have been calculated. By means of an association parameter A, association of phenol molecules with respect to various parts of the molecule has been established. Closest distances of approach between protons and configurations of maximum occurrence probabilities are reported.

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Authors and Affiliations

  1. Institut für Physikalische Chemie und Elektrochemie der Universität Karlsruhe, Kaiserstr. 12, D-7500, Karlsruhe, West Germany

    W. Koch, H. Leiter & H. G. Hertz

Authors
  1. W. Koch
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  2. H. Leiter
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  3. H. G. Hertz
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Koch, W., Leiter, H. & Hertz, H.G. A study of association by hydrogen bonding in the system phenol-CCl4 by the nuclear magnetic relaxation method. J Solution Chem 10, 419–430 (1981). https://doi.org/10.1007/BF00658010

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  • DOI: https://doi.org/10.1007/BF00658010

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