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Raman spectral study of the constitution and equilibria of nitric acid and d-nitric acid

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Abstract

From relative integrated intensity measurements of the symmetric stretching vibration of nitrate ion in nitric acid solutions (both HNO 3 /H 2 O and DNO 3 /D 2 O), the mass law concentration quotients, Q ć were obtained as functions of concentration. By extrapolation the limiting dissociation constants were estimated to be 24.4 and 15 respectively at 25°C. It is shown that this constant refers to a process in which the ion pair H 3 O+ NO − 3 is in equilibrium with the dispersed, solvated H 3 O+ and NO − 3 ions.

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Authors and Affiliations

  1. Guelph-Waterloo centre for Graduate Work in Chemistry, Department of Chemistry, University of Waterloo, N2L 3G1, Waterloo, Ontario, Canada

    Donald E. Irish & Olga Puzic

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  1. Donald E. Irish
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  2. Olga Puzic
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Irish, D.E., Puzic, O. Raman spectral study of the constitution and equilibria of nitric acid and d-nitric acid. J Solution Chem 10, 377–393 (1981). https://doi.org/10.1007/BF00658007

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  • DOI: https://doi.org/10.1007/BF00658007

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