Colloid and Polymer Science

, Volume 269, Issue 9, pp 923–928 | Cite as

On the theory of adsorption kinetics of ionic surfactants at fluid interfaces 3. Generalization of the model

  • S. S. Dukhin
  • R. Miller
Original Contributions


It was shown that, in the case of adsorbing ions, the Boltzmann equation cannot be applied in its classical form, but has to be modified by considering the flux of adsorbing ions. From the comparison with the adsorption of nonionic surfactants a ratio results which is the measure of deceleration of adsorption kinetics due to the electric double layerr=K(ys)/δ(t). At highr-values the electrostatic deceleration controls the adsorption kinetics process.

Key words

Adsorptionkinetics theory ionicsurfactants 


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Copyright information

© Steinkopff Verlag 1991

Authors and Affiliations

  • S. S. Dukhin
    • 1
  • R. Miller
    • 2
  1. 1.Institute of Colloid and Water Chemistry of the Ukrainian Academy of SciencesKiev
  2. 2.Central Institute of Organic ChemistryBerlin-Adlershof

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