Abstract
Microcalorimetry was used to study the interaction between gaseous oxygen and NiO single crystals. The studies involved consecutive sorption of small and large oxygen doses at 1000 K. Fast and slow processes of oxygen incorporation into NiO were distinguished. The fast process involved oxygen sorption in the near-surface layer. Then oxygen incorporation was ratecontrolled by a slow lattice diffusion in the crystalline bulk. A power of oxygen pressure dependence was found (1/n = 1/4.25) which was consistent with the defect structure of NiO. Heat of formation of cation vacancies was determined [ΔHf=155 kJ/mole].
Similar content being viewed by others
References
J. B. Price and J. B. Wagner, Jr.,Z. Phys. Chem. N.F. 49, 257 (1960).
S. P. Mitoff,J. Chem. Phys. 35, 882 (1961).
I. O. Tretjakov and R. A. Rapp,Trans. Metall. Soc. AIME,245, 1235 (1969).
C. M. Osburn and R. W. Vest,J. Phys. Chem. Solids,32, 1331 (1970).
W. C. Tripp and N. M. Tallan,J. Am. Ceram. Soc. 53, 531 (1970).
J. Bransky and N. M. Tallan,J. Chem. Phys. 49, 1243, (1968).
G. H. Meier and R. A. Rapp,Z. Phys. Chem. N.F. 74, 168 (1971).
J. Nowotny,J. Chem. Phys. 75, 6, (1978).
N. G. Error and J. B. Wagner, Jr.,Phys. Stat. Solidi,35, 644 (1969).
J. Dereń, Z. Jarzebski, S. Mrowec, and T. Walec,Bull Acad. Polon. Sci., Ser. Sci. Chim. 19, 147 (1971).
C. M. Osborn and R. W. Vest,J. Phys. Chem. Solids,2, 1343, (1971).
J. Nowotny and M. Rekas, in press. consumed.
A. J. Bosman and C. CrevecoeurPhys. Rev. 144, 763 (1966).
H. G. Sockel and H. Schmalzried,Ber. Bunsenges. Phys. Chem. 72, 745 (1968).
S. Pizzini and R. Morlotti,J. Electrochem. Soc. 114, 1170 (1967).
J. Dereń, M. Rékas, and G. Róg,Ann. Chem. Polon., in press.
A. J. Bosman, N. J. Daal, and G. F. Knuvers,Phys. Lett. 19, 5 (1965).
I. G. Austin, A. J. Springhorpe, B. A. Smith, C. E. Turner,Proc. Phys. Soc. 2, 1418 (1968).
P. Odier,Proceedings of the 9th International Symposium on Reactivity of Solids (Elsevier, New York, 1978), p. 53.
P. C. Gravelle S. J. Teichner,Adv. Catal. 20, 167 (1978).
P. C. Gravelle, G. Marty, S. J. Teichner,Proceedings of the 1stInternational Conference on Calorimetry and Thermodynamics Warsaw, 1969, (1971), p. 365.
R. Lalauze and J. Meunier,Ann. Chim. Fr. 197 (1979).
J. Nowotny and A. Sadowski,J. Am. Ceram. Soc. 62, 24 (1979).
C. Wagner,J. Electrochem. Soc. 103, 627 (1956).
M. Perlinska, Ph.D. thesis, Kracow (1977).
J. Meunier, Ph.D. thesis, Saint-Etienne (1979).
H. G. Sockel and B. Ilchner,Z. Physik. Chem. N.F. 74, 284 (1971).
R. Uno,J. Phys. Soc. Jpn. 22, 1501 (1967).
G. J. Koel, P. J. Geilings,Oxid. Met. 5, 185 (1972).
M. L. Volpe and J. Reddy,J. Chem. Phys. 53, 1117 (1970).
J. T. Cox and C. M. Quinn,J. Mater. Sci. 4, 33 (1968).
Y. Ikeda, K. Nii, G. Beranger, and P. Lacombe,Trans. Jpn. Inst. Metals,15, 441 (1974).
J. Nowotny and J. B. Wagner, Jr.,Bull. Acad. Polon. Sci. Ser. Sci. Chim. 19, 93 (1973).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Lalauze, R., Soustelle, M., Rekas, M. et al. Application of microcalorimetry in studies of interaction between oxygen and NiO single crystals. Oxid Met 20, 241–253 (1983). https://doi.org/10.1007/BF00656843
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF00656843