Journal of inclusion phenomena

, Volume 5, Issue 2, pp 283–287 | Cite as

Synthesis, crystallographic, and thermal properties of a new porous silica

Zeclites

Abstract

A new porous tectosilicate has been synthesized in the presence of boric acid and 1, 2, 2, 6, 6-pentamethylpiperidine as guest molecules. It crystallizes in the monoclinic system with ao=9.91 (1) Å, bo=20.62 (3) Å, co=9.80 (2) Å, and β-99.7 (2)0. After heat treatment at 820°C for 1 hour the guest molecules are set free whereas the silica host framework is retained. From crystal morphology and thermal behaviour it is concluded that the new material possesses channel-like voids.

Keywords

Heat Treatment Organic Chemistry Thermal Property Thermal Behaviour Boric Acid 

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References

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    R. M. Barrer in proceedings of the 7th International Zeolite Conference, Tokyo, 1 (1986), Elsevier New York, Amsterdam, Oxford. F. Liebau, H. Gies, R.P. Gunawardane, and B. Marler, Zeolites, in press.Google Scholar
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Copyright information

© D. Reidel Publishing Company 1987

Authors and Affiliations

  • H. Gies
    • 1
  1. 1.Mineralogisches Institut der Universität KielKielGermany

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