Journal of Applied Spectroscopy

, Volume 3, Issue 1, pp 30–34 | Cite as

Vibrational spectra of crystalline potassium ferri- and ferrocyanide

  • Yu. A. Klyuev
Article

Abstract

The IR spectra of the crystalline salts K3[Fe(CN)6] (I) and K4[Fe(CN)6] (II) have been studied in the 1600–5000 cm−1 range for the purpose of investigating the spectral difference in the valence states of the central atoms of the complex anions. The appearance of the doublet structure of thev6 band in the spectrum of salt II is due to distortion of its anion to D4h symmetry. The vibrational spectra of both salts are interpreted.

Keywords

Potassium Analytical Chemistry Molecular Structure Valence State Vibrational Spectrum 

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References

  1. 1.
    J. P. Mathieu and S. Cornevin, J. Chem. Phys., 36, 271, 1939.Google Scholar
  2. 2.
    J. P. Mathieu, J. Chem. Phys., 37, 308, 1939.Google Scholar
  3. 3.
    G. Emschwiller, Compt. Rend., 238, 1414, 1954.Google Scholar
  4. 4.
    N. I. Hawkins, H. C. Mattraw, W. W. Sabol, and D. R. Carpenter, J. Chem. Phys., 23, 2422, 1955.Google Scholar
  5. 5.
    J. P. Mathieu, J. Inorg. Nucl. Chem., 8, 33, 1958.Google Scholar
  6. 6.
    A. Hidalgo and J. P. Mathieu, C. R.. 249, 233, 1959.Google Scholar
  7. 7.
    L. H. Jones, J. Chem. Phys., 37, 1209, 1962.Google Scholar
  8. 8.
    V. Cagliotti, G. Sartori, and M. Scrocco, Atti acad. naz. lincei, Rend. sc. fis., 23, 355, 1957; 25, 260, 1958.Google Scholar
  9. 9.
    J. Nakagawa and T. Shimanouchi, Spectroch. Acta, 18, 101, 1962.Google Scholar
  10. 10.
    V. Cagliotti, G. Sartori, and M. Scrocco, J. Inorg. Nucl. Chem., 8, 87, 1958.Google Scholar
  11. 11.
    R. S. Halford, J. Chem. Phys., 14, 8, 1946.Google Scholar
  12. 12.
    G. B. Bonino and G. Fabri, Atti acad. naz. lincei, Rend. sc. fis., 19, 386, 1955.Google Scholar
  13. 13.
    I. B. Bersuker, ZhSKh, 2, 350, 1961; 3, 64, 1962.Google Scholar
  14. 14.
    B. F. Ormont, Inorganic Structure [in Russian], GITTL, p. 279, 1950.Google Scholar
  15. 15.
    Yu. A. Klyuev and A. M. Vorob'ev, DAN SSSR, 158, 1396, 1964.Google Scholar
  16. 16.
    I. B. Bersuker and B. G. Vekher, Izv. AN MoldSSR, no. 10, 11, 1962.Google Scholar

Copyright information

© The Faraday Press, Inc. 1967

Authors and Affiliations

  • Yu. A. Klyuev

There are no affiliations available

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