Skip to main content
SpringerLink
Log in

A small angle neutron scattering study of the sodium di-n-pentyl phosphate micelles in water

  • Original Contribution
  • Published:
Colloid and Polymer Science Aims and scope Submit manuscript

Abstract

Small angle neutron scattering has been used to elucidate the size and shape of a micelle in the sodium di-n-pentyl phosphate (DPP)-water system. The results are summarized as follows. For the DPP micelle, the aggregation number (n) depends on the concentration (n=12, at 7.0 wt% andn=15 at 10.0 wt%). The minimum micelle is spherical and has an aggregation numbern=7. For the DPP-micellar system, it can be assumed that micellar growth and variation from the spherical to probate shape occurs with an increase in concentration above the CMC.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Nakagaki M, Handa T (1975) Bull Chem Soc Jpn 48:630–635

    Google Scholar 

  2. Kunitake T, Okahata Y (1977) J Amer Chem Soc 99:3860–3861

    Google Scholar 

  3. Kunitake T, Okahata Y (1978) Bull Chem Soc Jpn 51:1877–1879

    Google Scholar 

  4. Kano K, Romero A, Diermouni B, Ache HJ, Fendler JH (1979) J Amer Chem Soc 101:4030–4037

    Google Scholar 

  5. Shimomura M, Kunitake T (1982) J Am Chem Soc 104:1757–1759

    Google Scholar 

  6. Wagenaar A, Rupert LAM, Engberts JBFN, Hoekstra D (1989) J Org Chem 54:2638–2642

    Google Scholar 

  7. Sudholter EJR, Engberts JBFN, Hoekstra D (1980) J Amer Chem Soc 102:2467–2469

    Google Scholar 

  8. Sudholter EJR, de Grip WJ, Engberts JBFN (1982) J Amer Chem Soc 104:1069–1072

    Google Scholar 

  9. Rupert LAM, Hoekstra D, Engberts JBFN (1985) J Amer Chem Soc 107: 2628–2631

    Google Scholar 

  10. Rupert LAM, Van Breemen JFC, Van Bruggen EFJ, Engberts JBFN, Hoekstra D (1987) J Membr Biol 95:255–263

    Google Scholar 

  11. Rupert LAM, Hoekstra D, Engberts JBFN (1987) J Colloid Interface Sci 120:125–134

    Google Scholar 

  12. Shimanouchi T, Tsuboi M, Kyogoku Y (1964) Adv Chem Phys 7:435–498

    Google Scholar 

  13. Okabayashi H, Yoshida T, Ikeda T, Matsuura H, Kitagawa T (1982) J Amer Chem Soc 104:5399–5402

    Google Scholar 

  14. Okabayashi H, Taga K, Miyagai K, Uehara T, Yoshida T, Nishio E (1991) J Phys Chem 95:7932–7938

    Google Scholar 

  15. Okabayashi H, Okuyama M, Kitagawa T (1975) Bull Chem Soc Jpn 48:2264–2269

    Google Scholar 

  16. Okabayashi H, Taga K, Tsukamoto K, Tamaoki H, Yoshida T, Matsuura H (1985) Chemica Scripta 25:153–156

    Google Scholar 

  17. McCombie H, Saunders BC, Stacey GJ (1945) J Chem Soc, 380–382

  18. Mukaiyama T, Fujisawa T (1961) Bull Chem Soc Jpn 34:812–813

    Google Scholar 

  19. Vass S, Török T, Jákli G, Berecz E (1989) J Phys Chem 93:6553–6559

    Google Scholar 

  20. Marcus YJ (1983) J Solution Chem 12:271–275

    Google Scholar 

  21. Suzuya K (1992) Ph D thesis, Tohoku University

  22. Hirata H, Aoki S, Taga K, Okabayashi H, Yoshida T, to be published

  23. Bendedoch D, Chen SH (1984) J Phys Chem 88:648–652

    Google Scholar 

  24. Tanford C (1972) J Phys Chem 76: 3020–3024

    Google Scholar 

  25. Hayter JB, Penfold J (1981) Mol Phys 42:109–118

    Google Scholar 

  26. Hansen J, Hayter JB (1982) Mol Phys 46:651–656

    Google Scholar 

  27. Kotlarchyk M, Chen SH (1983) J Phys Chem 79:2461–2469

    Google Scholar 

  28. Chen SH, Lin TL (1987) Method of Experimental Physics Vol 23, PART B, Chapt 16 Academic Press

  29. Missel PJ, Mazer NA, Benedek GB, Young CY, Carrery MC (1980) J Phys Chem 84:1044–1057

    Google Scholar 

  30. Shew EY, Chen SH, Huang JS (1987) J Phys Chem 91:3306–3310

    Google Scholar 

  31. Burkitt SJ, Ottewill RH, Hayter JB, Ingram BT (1987) Colloid Polym Sci 256:619–627

    Google Scholar 

  32. Israelachvili J (1992) Intermolecular & Surface Forces, Chap 16∼17 Academic Press

  33. Kamo O, Matsushita K, Terada Y, Yoshida T, Okabayashi H (1984) Chem Scripta 23:189–194

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Applied Chemistry, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, 466, Nagoya, Japan

    H. Hirata & H. Okabayashi

  2. BSF, National Laboratory for High Energy Physics, 1-1 Oho, 305, Tsukuba-shi Ibaraki, Japan

    M. Furusaka

  3. Department of Physics, Tokyo Metropolitan University, 192-03, Hachioji Tokyo, Japan

    T. Kawakatsu

Authors
  1. H. Hirata
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. H. Okabayashi
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. Furusaka
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. T. Kawakatsu
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Hirata, H., Okabayashi, H., Furusaka, M. et al. A small angle neutron scattering study of the sodium di-n-pentyl phosphate micelles in water. Colloid Polym Sci 273, 1193–1200 (1995). https://doi.org/10.1007/BF00653089

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00653089

Key words

Search

Navigation