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Journal of Solution Chemistry

, Volume 19, Issue 9, pp 945–955 | Cite as

Frequency dependent conductance and dielectric permittivity

  • Werner Ebeling
  • Jean-Claude Justice
Article
  • 74 Downloads

Abstract

Starting from the basic equation for the pair distribution function in nonequilibrium which takes into account the echo effect, the theory of electrolytes in low frequency fields is investigated. For explicit calculations of the pair distribution functions, the strong coupling approximation (SCA) for distances smaller than the Bjerrum distance is used. The result is discussed as the effect of ionic motion on the complex permittivity of the solution. In the limiting case of large values of the Bjerrum parameier it identifies with the effect of rotating ion pairs and allows an evaluation of the increase on the static permittivity of the electrolyte solutions.

Key Words

Electrolyte solution frequency conductance dielectric permittivity ion pairing rotation dipoles strong coupling feedback or echo theory 

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References

  1. 1.
    H. Falkenhagen,Theorie der Elektrolyte (Hirzel, Leipzig 1971).Google Scholar
  2. 2.
    W. D. Kraeft,Ann. Phys. (Leipzig) 19, 197 (1967).Google Scholar
  3. 3.
    J.-P. Badiali, H. Cachet, A. Cyrot, and J.-C. Lestrade,J. Chem. Faraday Trans. II 69, 1339 (1973);72, 1231 (1976); H. Cachet and J.-C. Lestrade,Bull. Soc. Chim. Belg. 85, 481 (1969).Google Scholar
  4. 4.
    R. Pottel and U. Kaatze,Ber. Bunsenges. Phys. Chem. 73, 437 (1969); E. A. S. Cavell,Trans. Faraday Soc. 61, 1578 (1965); E. A. S. Cavell, P. C. Knight, and M. A. Scheikh,Trans. Faraday Soc. 67, 2225 (1971); E. A. S. Cavell and P. C. Kight,J. Chem. Soc. Faraday Trans. II 63, 765 (1972).Google Scholar
  5. 5.
    J.-P. Badiali and M. L. Rosinberg,Comp. Rend. Acad. Sci. 276 B, 825 (1973); J.-P. Badiali, H. Cachet, A. Cyrot, and J.-C. Lestrade, inMolecular Motions in Liquids, J. Lascombe, ed., (Reide, Dordrecht 1974).Google Scholar
  6. 6.
    J.-C. Justice,J. Solution Chem. 11, 859 (1978).Google Scholar
  7. 7.
    J.-C. Justice and W. Ebeling,J. Solution Chem. 11, 809 (1979).Google Scholar
  8. 8.
    W. Ebeling and W. D. Kraeft,Z. Phys. Chem. (Leipzig) 233, 388 (1968).Google Scholar
  9. 9.
    W. Ebeling and J.-C. Justice,Rostocker Physikal. Manuskripte 4, 133 (1979).Google Scholar
  10. 10.
    W. Ebeling, R. Feistel, G. Kelbg, and R. Sändig,J. Nonequil. Thermodyn. 3, 11 (1978);J. Solution Chem. 8, 53 (1979).Google Scholar
  11. 11.
    R. Cachet, A. Cyrot, M. Feker, and J. C. Lestrade,J. Phys. Chem. 83, 3419 (1979).Google Scholar

Copyright information

© Plenum Publishing Corporation 1990

Authors and Affiliations

  • Werner Ebeling
    • 1
  • Jean-Claude Justice
    • 2
  1. 1.Sektion Physik der Humboldt-UniversitätBerlin, PSF 1297GDR
  2. 2.Laboratoire d'ElectrochimieUniversité Pierre et Marie CurieParis, Cedex 05France

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