Abstract
The excess volumes of mixing of cyclohexylamine with n-hexane, n-heptene, n-octane, n-nonane, benzene, toluene, nitrobenzene, chlorobenzene and bromobenzene have been measured at 30°C. For all systems except for n-hexane, VE is positive over the entire mole fraction range. For the n-hexane mixtures, a sigmoid curve is obtained with negative VE at high mole fraction of amine.
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G. Narayanaswamy, G. Dharmaraju, and G. K. Raman,Can. J. Chem. 58, 3, 229 (1980);J. Chem. Thermodyn. 12, (1980), in press.
T. M. Letcher,J. Chem. Thermodyn. 4, 159 (1972).
E. Kauer, D. Klemm, D. Körnig, K. Mörke, D. Stephan, and H.-J. BittrichZ. Phys. Chem. (Leipzig) 252, 125 (1973).
J. A. Riddick and W. B. Bunger,Organic Solvents, 3rd edn. (Wiley-Interscience, New York, 1970).
A. Vogel,Practical Organic Chemistry (Longman Green and Co., London, 1968).
J. Timmermans,Physico-chemical Constants of Pure Organic Compounds (Elsevier, New York, 1950).
M. V. P. Rao and P. R. Naidu,Can. J. Chem. 52, 788 (1974).
R. H. Stokes, B. J. Levien, and K. N. Marsh,J. Chem. Thermodyn. 2, 43 (1970).
G. Pannetier, M. Kern, L. Abello, and G. Djega-Mariadassou,C. R. Acad. Sci., Paris, Ser. C. 264, 1016 (1967).
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Raju, G.D., Swamy, G.N. & Raman, G.K. Excess thermodynamic properties of binary liquid mixtures containing cyclohexylamine at 30°C. J Solution Chem 10, 79–82 (1981). https://doi.org/10.1007/BF00652782
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DOI: https://doi.org/10.1007/BF00652782