Skip to main content
Log in

Excess thermodynamic properties of binary liquid mixtures containing cyclohexylamine at 30°C

  • Published:
Journal of Solution Chemistry Aims and scope Submit manuscript

Abstract

The excess volumes of mixing of cyclohexylamine with n-hexane, n-heptene, n-octane, n-nonane, benzene, toluene, nitrobenzene, chlorobenzene and bromobenzene have been measured at 30°C. For all systems except for n-hexane, VE is positive over the entire mole fraction range. For the n-hexane mixtures, a sigmoid curve is obtained with negative VE at high mole fraction of amine.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. G. Narayanaswamy, G. Dharmaraju, and G. K. Raman,Can. J. Chem. 58, 3, 229 (1980);J. Chem. Thermodyn. 12, (1980), in press.

    Google Scholar 

  2. T. M. Letcher,J. Chem. Thermodyn. 4, 159 (1972).

    Google Scholar 

  3. E. Kauer, D. Klemm, D. Körnig, K. Mörke, D. Stephan, and H.-J. BittrichZ. Phys. Chem. (Leipzig) 252, 125 (1973).

    Google Scholar 

  4. J. A. Riddick and W. B. Bunger,Organic Solvents, 3rd edn. (Wiley-Interscience, New York, 1970).

    Google Scholar 

  5. A. Vogel,Practical Organic Chemistry (Longman Green and Co., London, 1968).

    Google Scholar 

  6. J. Timmermans,Physico-chemical Constants of Pure Organic Compounds (Elsevier, New York, 1950).

    Google Scholar 

  7. M. V. P. Rao and P. R. Naidu,Can. J. Chem. 52, 788 (1974).

    Google Scholar 

  8. R. H. Stokes, B. J. Levien, and K. N. Marsh,J. Chem. Thermodyn. 2, 43 (1970).

    Google Scholar 

  9. G. Pannetier, M. Kern, L. Abello, and G. Djega-Mariadassou,C. R. Acad. Sci., Paris, Ser. C. 264, 1016 (1967).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Raju, G.D., Swamy, G.N. & Raman, G.K. Excess thermodynamic properties of binary liquid mixtures containing cyclohexylamine at 30°C. J Solution Chem 10, 79–82 (1981). https://doi.org/10.1007/BF00652782

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00652782

key Words

Navigation