Abstract
Solubilities of carbon dioxide in aqueous ethanol solutions, determined at 15, 20, 25, 30 and 35°C at atmospheric pressure, show a minimum at each temperature. Thermodynamics functions for the solution process were calculated and compared with the predictions of the Pierotti gas solubility theory. The abnormal behavior of these solutions is demonstrated.
Similar content being viewed by others
References
J. P. O'Connell and J. M. Prausnitz,Ind. Eng. Chem. Fundamental 3, 347 (1964).
T. Boublik and E. Hala,Coll. Czech. Chem. Commun. 31, 1628 (1966).
J. P. O'Connell,A.I.Ch.E.J. 17, 658 (1971).
J. G. Kirkwood and F. P. Buff,J. Chem. Phys. 19, 774 (1951).
E. W. Tiepel and K. E. Gubbins,Can. J. Chem. Eng. 50, 361 (1972).
R. A. Pierotti,J. Phys. Chem. 67, 1840 (1963) and69, 281 (1965).
M. A. Postigo, G. C. Pedrosa, and M. Katz,Anal. Asoc. Quim. Argentina 66, 25 (1978).
International Critical Tables, (1929).
R. Battino and H. L. Clever,Chem. Rev. 66, 395 (1966).
R. E. Gibbs and H. C. Van Ness,Ind. Eng. Chem. Fundamentals 10, 312 (1971).
C. L. de Ligny and N. C. van der Veen,J. Solution Chem. 4, 841 (1975).
N. A. Lange,Handbook of Chemistry, (Handbook Publishers, Inc., Sandusky, Ohio, 1956).
H. A. Schowalter and J. B. Ferguson,Can. J. Res. 14B, 120 (1936).
J. A. Muccitelli and W. Yang Wen,J. Solution Chem. 9, 141 (1980).
A. Ben Naim and S. Baer,Trans. Faraday Soc. 60, 1736 (1964).
S. Tokunaga,J. Chem. Eng. Data 20, 41 (1975).
E. Sada, S. Kito, and Y. Ito,Ind. Eng. Chem. Fundamentals 14, 232 (1975).
J. M. Prausnitz,Molecular Thermodynamics of Fluid-Phase Equilbria (Prentice Hall, New York, 1969).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Postigo, M.A., Katz, M. Solubility and thermodynamics of carbon dioxide in aqueous ethanol solutions. J Solution Chem 16, 1015–1024 (1987). https://doi.org/10.1007/BF00652585
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF00652585