Abstract
We have prepared polypyrrole both as a bulk powder and as a sterically stabilised colloidal dispersion in a noved non-aqueous solvent, 2-merhoxyethanol. The steric stabiliser utilised in the latter system was a poly(vinyl acetate) homopolymer. The electroactivity, morphology, thermal stability and chemical composition of these materials were characterised by d.c. conductivity measurememts, electron microscopy, thermogravimetry, FTIR and visible absorption spectroscopy and clemental microanalyses. The mass ratio of poly(vinyl acetate) to polypyrrole in the colloidal particles was determined indirectly by spectroscopic assay of the post-reaction supernatant solution for non-adsorbed stabiliser.
Similar content being viewed by others
References
See for example, the conference proceedings of the ICSM 1988, M. Aldissi (ed.), Synth Met, 1989, 27–29, and references therein
Naarman H, Heckman W, Kohler G, Simak P Jan. 28 (1986). U.S. patent no. 4,567, 250, BASF
Myers RE (1986) J Electron Mater 2:61
Walker JA, Warren LF, Witucki EF (1987) ACS Polym Prepr 28(2):256
Armes SP (1987) Synth Met 20(3):367
Castillo-Ortega MM, Inoue MB, Inoue M (1989) Synth Met 28:65
Bjorklund RB, Lundstrom I (1984) J Electron Mater 13:211
Ojio T, Miyata S (1986) Polym J 18:95
Morita M, Hashida I, Nishimura M (1988) J Appl Polym Sci 36:1693
Chan HSO, Hor TSA, Hor PKH, Tan KL, Tan BTG (1990) J Macromol Sci-Chem A 27(8):1081
Yoshikawa T, Machida S, Ikegami T, Techagumpuch A, Miyata S (1990) Polym J 22(1):1
Armes SP, Vincent B (1987) J Chem Soc, Chem Commun 288
Armes SP, Miller JF, Vincent B (1987) J Coll Interface Sci 118(2):410
Armes SP, Aldissi M, Agnew SF (1989) Synth Met 28:837
Armes SP, Aldissi M (1990) Polymer 31:569
Armes SP, Aldissi M (1989) J Chem Soc, Chem Commun 89
Bjorklund RB, Liedberg B (1986) J Chem Soc, Chem Commun 1293
Cawdery N, Obey TM, Vincent B (1988) J Chem Soc, Chem Commun 1189;
Markham G, Obey TM, Vincent B (1990) Coll Surf 51:239
Epron F, Henry F, Sagnes O (1990) Makromol Chem Macromol Symp 35/36:527
Armes SP, Aldissi M, Idzorek GC, Keaton PW, Rowton LJ, Stradling GL, Collopy MT, McColl DB (1991) J Coll Interface Sci 141:119
Armes SP, Aldissi M (1990) Synth Met 37:137
Hayashi S, Kawamura C, Takayama M (1970) Bull Chem Soc Jpn 43:537
Dhinga E (1990) B.Sc. thesis, University of Sussex
Armes SP, Aldissi M, unpublished results
Armes SP, Aldissi M, Hawley M, Beery JG, Gottesfeld S (1991) Langmuir 7:1447
Beaman M (1991) B.Sc. thesis, University of Sussex
The Aldrich Library of FTIR Spectra, edition 1, edited by Pouchert CJ, 2:1183 (1985)
Armes SP (1987) Ph.D. thesis, University of Bristol
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Beaman, M., Armes, S.P. Preparation and characterisation of polypyrrole colloids in non-aqueous media. Colloid Polym Sci 271, 70–75 (1993). https://doi.org/10.1007/BF00652305
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00652305