Colloid and Polymer Science

, Volume 273, Issue 7, pp 648–652 | Cite as

Studies on model oligosulfides to understand polysulfide polymers

  • K. Ganesh
  • K. Kishore
Original Contribution

Abstract

1-bromo-1-phenylethane was reacted with aqueous sodium disulfide or sodium tetrasulfide to form the 1-phenylethyl polysulfides of sulfur rank 2 or 4 respectively. The distribution of the 1-phenylethyl polysulfides thus formed was studied using1H NMR and GC-MS analysis. Apart from 1-phenylethyl disulfide and 1-phenylethyl tetrasulfide being produced in large amounts when aqueous sodium disulfide and sodium tetrasulfide were used respectively, the formation of 1-phenylethyl monosulfide in the former case and both mono and disulfide in the latter case, in minor amounts, is also observed. Also, it was found that the undetection of the molecular ion peaks of 1-phenylethyl polysulfides having rank above 2 is due to their thermal decomposition to elemental sulfur, 1-phenylethyl mono and disulfide, under the heating conditions employed for GC-MS analysis.

Key words

Aqueous sodium disulfide aqueous sodium tetrasulfide sulfur rank-1-phenylethyl polysulfide total ion chromatogram (TIC) 

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References

  1. 1.
    Gobran RH, Berenbaum MB (1969) In: High Polymers Vol. XXIII, Kennedy JP, Tornquist EGM, Eds, Interscience, New YorkGoogle Scholar
  2. 2.
    Kishore K, Ganesh K (1995) Adv Polym Sci 121:81Google Scholar
  3. 3.
    Popielarz R, Arnold DR (1990) J Am Chem Soc 112:3068Google Scholar
  4. 4.
    Kishore K, Ganesh K (1993) Macromolecules 26:4700Google Scholar
  5. 5.
    Sander SR, Karo W (1980) In: Organic Chemistry: A series of monographys, Academic, New YorkGoogle Scholar
  6. 6.
    Harpp DN, Smith RA (1982) J Am Chem Soc 104:6045Google Scholar

Copyright information

© Steinkopff Verlag 1995

Authors and Affiliations

  • K. Ganesh
    • 1
  • K. Kishore
    • 1
  1. 1.Department of Inorganic and Physical ChemistryIndian Institute of ScienceBangaloreIndia

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