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Journal of Solution Chemistry

, Volume 10, Issue 7, pp 451–458 | Cite as

Standard molar enthalpies and volumes of adamantane in methanol, ethanol, acetone, andn-dodecane. Interpretation using the scaled-particle theory

  • Jean-Pierre Morel
  • Nicole Morel-Desrosiers
Article

Abstract

The volumes and enthalpies of solution of adamantane and of cyclohexane in methanol, ethanol, acetone, and n-dodecane have been measured as a function of concentration at 25°C. The standard molar volumes and enthalpies of adamantane have been resolved into cavity and interaction terms. The former have been calculated from the equations of the scaled-particle theory whereas the latter have been deduced from a model which assumes some proportionality between adamantane-solvent and cyclohexane-solvent interactions. The model, which had been previously verified with normal liquids, now also proves to be very satisfactory with solvents involving strong, nonadditive interactions.

Key words

Scaled-particle theory volume enthalpy of solution adamantane cyclohexane andn-dodecane methanol ethanol acetone 

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Copyright information

© Plenum Publishing Corporation 1981

Authors and Affiliations

  • Jean-Pierre Morel
    • 1
  • Nicole Morel-Desrosiers
    • 1
  1. 1.Laboratoire d'Etude des Interactions Solutés-SolvantsUniversité de Clermont 2AubièreFrance

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