Abstract
The system benzene-methanol was investigated at 25°C by the nuclear magnetic relaxation method. The total relaxation rates are separated into an intramolecular and an intermolecular part. The rotational and translational mobility of the components were studied. Strong OH...OH association has been confirmed.
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References
G. Scatchard, L. B. Ticknor, J. R. Goates, and E. R. McCartney,J. Am. Chem. Soc. 74, 3721 (1952).
F. Daniels and R. A. Alberty,Physical Chemistry, 4th edn. (Wiley, New York, 1975). Chapter 4.
H. G. Hertz, B. Kwatra, and R. Tutsch,Z. Phys. Chem. (Frankfurt) 103, 259 (1976).
A. L. Capparelli, H. G. Hertz, B. Kwatra, and R. Tutsch,Z. Phys. Chem. (Frankfurt) 103, 279 (1976).
A. Abragam,The Principles of Nuclear Magnetism (Clarendon Press, Oxford, 1961).
M. Grüner and H. G. Hertz,Adv. Mol. Relax. Proc. 9, 75 (1972);
H. G. Hertz and M. D. Zeidler, inThe Hydrogen Bond, P. Schuster, G. Zundel, and C. Sandorfy, eds. (North Holland Publishing Company, Amsterdam, 1976).
A. Gierer and K. Wirtz,Z. Naturforsch. Teil A 8, 582 (1953).
R. E. D. McClung and D. Kivelson,J. Chem. Phys. 49, 3380 (1968).
J. E. Anderson,J. Chem. Phys. 47, 4879 (1967);
J. E. Anderson and P. A. Fryer,J. Chem. Phys. 50, 3784 (1969).
D. E. Woessner,J. Chem. Phys. 36, 1 (1962);
D. E. Woessner, B. S. Snowden, Jr., and G. H. Meyer,J. Chem. Phys. 50, 719 (1969).
D. Wallach,J. Chem. Phys. 47, 5258 (1967).
H. Versmold,Z. Naturforsch. Teil A 25, 367 (1970).
A. R. Edmonds,Drehimpulse in der Quantenmechanik (Bibliographisches Institut, Mannheim, 1974);
M. E. Rose,Elementary Theory of Angular Momentum, (Wiley, New York, 1957).
T. C. Farrar and E. D. Becker,Pulse and Fourier Transform NMR (Academic Press, New York, 1971).
H. G. Hertz,Ber. Bunsenges. Phys. Chem. 80, 950 (1976).
H. G. Hertz and C. Rädle,Ber. Bunsenges. Phys. Chem. 77, 521 (1973).
A. Geiger, Dissertation, Karlsruhe (1973).
L. E. Drain,Proc. Phys. Soc. (London), Sect A 62, 301 (1949),
J. G. Powles,Proc. Phys. Soc. (London), Sect. A 71, 497 (1958)
J. G. Powles,Ber. Bunsenges. Phys. Chem. 67, 328 (1963),
W. A. Anderson, inNMR and EPR Spectroscopy (Varian Associates Pergamon Press, Oxford, 1960).
R. Freeman and D. W. Hill,J. Chem. Phys. 54, 3367 (1971).
M. Sass and D. Ziessow,J. Magn. Reson. 25, 263 (1977).
M. D. Zeidler,Ber. Bunsenges. Phys. Chem. 69, 659 (1965);
E. von Goldammer and M. D. Zeidler,Ber. Bunsenges. Phys. Chem. 73, 4 (1969).
G. Bonera and A. Rigamonti,J. Chem. Phys. 42, 171 (1965).
A. A. Brooks, J. D. Cutnell, E. O. Stejskal, and V. W. Weiss,J. Chem. Phys. 49, 1571 (1968).
K. Engelsmann, H. G. Hertz, and M. D. Zeidler,Z. Phys. Chem. (Frankfurt) 89, 134 (1974);
H. E. Simon and R. L. Vold,J. Magn. Reson. 24, 399 (1976);
A. Kratochwill and H. G. Hertz,J. Chim. Phys. 74, 814 (1977).
R. O. Inlov, M. D. Joesten, and J. R. van Wazer,J. Phys. Chem. 79, 2307 (1975).
G. C. Pimentel and A. L. McClellan,The Hydrogen Bond (Freeman, San Francisco, 1960);
A. T. Lemley,Chemistry of Non-aqueous Solvents, Vol. IV (Academic Press, New York, 1976).
T. A. Renner, G. H. Kucera, and M. Blander,J. Chem. Phys. 66, 177 (1977).
C. S. Caldwell and A. L. Babb,J. Phys. Chem. 59, 1113 (1955);
P. A. Johnson and A. L. Babb,J. Phys. Chem. 60, 14 (1956).
B. M. Fung and T. W. McGaughy,J. Chem. Phys. 65, 2970 (1976).
H. G. Hertz, R. Tutsch, and N. S. Bowman,J. Phys. Chem. 80, 417 (1976).
R. Göller, H. G. Hertz, and R. Tutsch,Pure Appl. Chem. 32, 149 (1972).
L. Rothardt,Z. Phys. Chem. (Leipzig) 204, 215 (1955);
J. Hurwic and W. Waclawek,Z. Phys. Chem. (Leipzig) 235, 240 (1967);
W. B. Dixon,J. Phys. Chem. 74, 1396 (1970).
W. G. Schneider,J. Phys. Chem. 66, 2653 (1962);
J. Ronayne and D. H. Williams,J. Chem. Soc. B, 540 (1967).
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Work done at Professor Hertz's laboratory in Karlsruhe on a leave from the Quaid-i-Azam University.
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Ansari, M.S., Kratochwill, A. A nuclear magnetic relaxation study of the system benzene-methanol. J Solution Chem 7, 655–668 (1978). https://doi.org/10.1007/BF00652016
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DOI: https://doi.org/10.1007/BF00652016