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A nuclear magnetic relaxation study of the system benzene-methanol

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Abstract

The system benzene-methanol was investigated at 25°C by the nuclear magnetic relaxation method. The total relaxation rates are separated into an intramolecular and an intermolecular part. The rotational and translational mobility of the components were studied. Strong OH...OH association has been confirmed.

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References

  1. G. Scatchard, L. B. Ticknor, J. R. Goates, and E. R. McCartney,J. Am. Chem. Soc. 74, 3721 (1952).

    Google Scholar 

  2. F. Daniels and R. A. Alberty,Physical Chemistry, 4th edn. (Wiley, New York, 1975). Chapter 4.

    Google Scholar 

  3. H. G. Hertz, B. Kwatra, and R. Tutsch,Z. Phys. Chem. (Frankfurt) 103, 259 (1976).

    Google Scholar 

  4. A. L. Capparelli, H. G. Hertz, B. Kwatra, and R. Tutsch,Z. Phys. Chem. (Frankfurt) 103, 279 (1976).

    Google Scholar 

  5. A. Abragam,The Principles of Nuclear Magnetism (Clarendon Press, Oxford, 1961).

    Google Scholar 

  6. M. Grüner and H. G. Hertz,Adv. Mol. Relax. Proc. 9, 75 (1972);

    Google Scholar 

  7. H. G. Hertz and M. D. Zeidler, inThe Hydrogen Bond, P. Schuster, G. Zundel, and C. Sandorfy, eds. (North Holland Publishing Company, Amsterdam, 1976).

    Google Scholar 

  8. A. Gierer and K. Wirtz,Z. Naturforsch. Teil A 8, 582 (1953).

    Google Scholar 

  9. R. E. D. McClung and D. Kivelson,J. Chem. Phys. 49, 3380 (1968).

    Google Scholar 

  10. J. E. Anderson,J. Chem. Phys. 47, 4879 (1967);

    Google Scholar 

  11. J. E. Anderson and P. A. Fryer,J. Chem. Phys. 50, 3784 (1969).

    Google Scholar 

  12. D. E. Woessner,J. Chem. Phys. 36, 1 (1962);

    Google Scholar 

  13. D. E. Woessner, B. S. Snowden, Jr., and G. H. Meyer,J. Chem. Phys. 50, 719 (1969).

    Google Scholar 

  14. D. Wallach,J. Chem. Phys. 47, 5258 (1967).

    Google Scholar 

  15. H. Versmold,Z. Naturforsch. Teil A 25, 367 (1970).

    Google Scholar 

  16. A. R. Edmonds,Drehimpulse in der Quantenmechanik (Bibliographisches Institut, Mannheim, 1974);

    Google Scholar 

  17. M. E. Rose,Elementary Theory of Angular Momentum, (Wiley, New York, 1957).

    Google Scholar 

  18. T. C. Farrar and E. D. Becker,Pulse and Fourier Transform NMR (Academic Press, New York, 1971).

    Google Scholar 

  19. H. G. Hertz,Ber. Bunsenges. Phys. Chem. 80, 950 (1976).

    Google Scholar 

  20. H. G. Hertz and C. Rädle,Ber. Bunsenges. Phys. Chem. 77, 521 (1973).

    Google Scholar 

  21. A. Geiger, Dissertation, Karlsruhe (1973).

  22. L. E. Drain,Proc. Phys. Soc. (London), Sect A 62, 301 (1949),

    Google Scholar 

  23. J. G. Powles,Proc. Phys. Soc. (London), Sect. A 71, 497 (1958)

    Google Scholar 

  24. J. G. Powles,Ber. Bunsenges. Phys. Chem. 67, 328 (1963),

    Google Scholar 

  25. W. A. Anderson, inNMR and EPR Spectroscopy (Varian Associates Pergamon Press, Oxford, 1960).

    Google Scholar 

  26. R. Freeman and D. W. Hill,J. Chem. Phys. 54, 3367 (1971).

    Google Scholar 

  27. M. Sass and D. Ziessow,J. Magn. Reson. 25, 263 (1977).

    Google Scholar 

  28. M. D. Zeidler,Ber. Bunsenges. Phys. Chem. 69, 659 (1965);

    Google Scholar 

  29. E. von Goldammer and M. D. Zeidler,Ber. Bunsenges. Phys. Chem. 73, 4 (1969).

    Google Scholar 

  30. G. Bonera and A. Rigamonti,J. Chem. Phys. 42, 171 (1965).

    Google Scholar 

  31. A. A. Brooks, J. D. Cutnell, E. O. Stejskal, and V. W. Weiss,J. Chem. Phys. 49, 1571 (1968).

    Google Scholar 

  32. K. Engelsmann, H. G. Hertz, and M. D. Zeidler,Z. Phys. Chem. (Frankfurt) 89, 134 (1974);

    Google Scholar 

  33. H. E. Simon and R. L. Vold,J. Magn. Reson. 24, 399 (1976);

    Google Scholar 

  34. A. Kratochwill and H. G. Hertz,J. Chim. Phys. 74, 814 (1977).

    Google Scholar 

  35. R. O. Inlov, M. D. Joesten, and J. R. van Wazer,J. Phys. Chem. 79, 2307 (1975).

    Google Scholar 

  36. G. C. Pimentel and A. L. McClellan,The Hydrogen Bond (Freeman, San Francisco, 1960);

    Google Scholar 

  37. A. T. Lemley,Chemistry of Non-aqueous Solvents, Vol. IV (Academic Press, New York, 1976).

    Google Scholar 

  38. T. A. Renner, G. H. Kucera, and M. Blander,J. Chem. Phys. 66, 177 (1977).

    Google Scholar 

  39. C. S. Caldwell and A. L. Babb,J. Phys. Chem. 59, 1113 (1955);

    Google Scholar 

  40. P. A. Johnson and A. L. Babb,J. Phys. Chem. 60, 14 (1956).

    Google Scholar 

  41. B. M. Fung and T. W. McGaughy,J. Chem. Phys. 65, 2970 (1976).

    Google Scholar 

  42. H. G. Hertz, R. Tutsch, and N. S. Bowman,J. Phys. Chem. 80, 417 (1976).

    Google Scholar 

  43. R. Göller, H. G. Hertz, and R. Tutsch,Pure Appl. Chem. 32, 149 (1972).

    Google Scholar 

  44. L. Rothardt,Z. Phys. Chem. (Leipzig) 204, 215 (1955);

    Google Scholar 

  45. J. Hurwic and W. Waclawek,Z. Phys. Chem. (Leipzig) 235, 240 (1967);

    Google Scholar 

  46. W. B. Dixon,J. Phys. Chem. 74, 1396 (1970).

    Google Scholar 

  47. W. G. Schneider,J. Phys. Chem. 66, 2653 (1962);

    Google Scholar 

  48. J. Ronayne and D. H. Williams,J. Chem. Soc. B, 540 (1967).

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Work done at Professor Hertz's laboratory in Karlsruhe on a leave from the Quaid-i-Azam University.

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Ansari, M.S., Kratochwill, A. A nuclear magnetic relaxation study of the system benzene-methanol. J Solution Chem 7, 655–668 (1978). https://doi.org/10.1007/BF00652016

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